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Perkin Transactions 2 1972-2002 logo

Year 1976
Main Index

Issue 0


Index of authors, 1976

pg 1925; DOI:
10.1039/P29760001925
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Index of subjects, 1976

pg 1945; DOI:
10.1039/P29760001945
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Issue 1


Front cover

pg X001; DOI:
10.1039/P297600FX001
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Contents pages

pg P001; DOI:
10.1039/P297600FP001
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Investigation of rotational isomerism in thiophen- and furan-2-carbonyl halides by nuclear magnetic resonance and infrared spectrometry
Derek J. Chadwick John Chambers G. Denis Meakins and Roger L. Snowden
pg 1; DOI:
10.1039/P29760000001
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Back cover

pg X003; DOI:
10.1039/P297600BX003
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Cyclobutanol: fragmentation ratios for the singlet and triplet excited states in the type II photochemistry of some -alkylated cyclohexanones
Ian Fleming Anthony V. Kemp-Jones William E. Long and Eric J. Thomas
pg 7; DOI:
10.1039/P29760000007
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Photosensitisation in the photolysis of saturated ketones
Ian Fleming and William E. Long
pg 14; DOI:
10.1039/P29760000014
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Comparison between the cyano-group hydrogen bonding abilities, infrared frequencies, and intensities in some -alkylthio-nitriles
Marino T. Fabi Liliana Marzorati Paulo R. Olivato Roberto Rittner Hans Viertler and Blanka Wladislaw
pg 16; DOI:
10.1039/P29760000016
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Liquid crystal nuclear magnetic resonance investigation on the structure of a molecule formed by two fused six-membered rings: 2, 7-naphthyridine
Roberto Danieli Lodovico Lunazzi and C. Alberto Veracini
pg 19; DOI:
10.1039/P29760000019
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Radiation mechanisms. Part VII. Electron-loss and -capture processes in phenylphosphinic acid and related compounds
Shuddhodan P. Mishra and Martyn C. R. Symons
pg 21; DOI:
10.1039/P29760000021
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Photochemistry of chlorpromazine [2-chloro-N-(3-dimethylaminopropyl)phenothiazine] in propan-2-ol solution
A. Keith Davies Suppiah Navaratnam and Glyn O. Phillips
pg 25; DOI:
10.1039/P29760000025
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Purine studies. Part XVI. Occurrence of syn- and anti-isomers in 4-amino-5-formamidopyrimidine derivatives
M. David Fenn and John H. Lister
pg 29; DOI:
10.1039/P29760000029
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Crystal and molecular structure of 4-aminotetrolic acid (4-aminobut-2-ynoic acid)
Graham P. Jones and Peter J. Pauling
pg 32; DOI:
10.1039/P29760000032
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Crystal and molecular structure of imidazole-4-acetic acid hydrochloride
Graham P. Jones and Peter J. Pauling
pg 34; DOI:
10.1039/P29760000034
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Thermal isomerization of benzene cis-trioxide (3,6,9-trioxatetracyclo[6.1.0.0.0]nonane)
David E. Penny
pg 36; DOI:
10.1039/P29760000036
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Inter- and intra-molecular catalysis in the enolization of derivatives of 2-carboxyacetophenone
Ronald P. Bell Derek W. Earls and John B. Henshall
pg 39; DOI:
10.1039/P29760000039
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Intramolecular catalysis in the detritiation of 2,6-dihydroxyacetophenone and 2-hydroxyacetophenone
Ronald P. Bell and Derek W. Earls
pg 45; DOI:
10.1039/P29760000045
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Amine oxidation. Part IX. The electrochemical oxidation of some tertiary amines: the effect of structure on reactivity
John R. Lindsay Smith and David Masheder
pg 47; DOI:
10.1039/P29760000047
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The kinetics of reversible Diels–Alder reactions in the gas phase. Part II. Cyclopentadiene and ethylene
Robin Walsh and Jean M. Wells
pg 52; DOI:
10.1039/P29760000052
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Mechanistic studies in strongly basic media. Part IX. Patterns of reactivity of sodium salts of 9-substituted fluorenes with molecular oxygen and with acrylic esters
Donald Bethell Colin S. Fairclough Robert J. E. Talbot and Rodney G. Wilkinson
pg 55; DOI:
10.1039/P29760000055
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Free radical addition to olefins. Part XVIII. Addition of chloroiodo- and di-iodo-methane to fluoroalkenes
Norman McMurray John M. Tedder Luc L. T. Vertommen and John C. Walton
pg 63; DOI:
10.1039/P29760000063
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Kinetics of reaction of substituted pyridines and oxygen anions with methyl chloroformate in aqueous solution
Patricia M. Bond Enrique A. Castro and Roy B. Moodie
pg 68; DOI:
10.1039/P29760000068
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Polyhalogenoaromatic compounds. Part XXXVI. Mass spectra of octa- and hepta-chloronaphthalenes
Jim Clark Ruth Maynard and Basil J. Wakefield
pg 73; DOI:
10.1039/P29760000073
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Nitroxide radicals. Part XVIII. Further spectroscopic investigation of the Banfield and Kenyon nitroxide
Peter J. Baldry Alexander R. Forrester and Ronald H. Thomson
pg 76; DOI:
10.1039/P29760000076
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The electronic structure of the quinonoid bicyclic heterocycles isoindole, benzo[c]furan, benzo[c]thiophen, and 2H-indene
Michael H. Palmer and Sheila M. F. Kennedy
pg 81; DOI:
10.1039/P29760000081
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Quantitative aspects of Lewis acidity. Part XV. Basicity of substituted pyridines and quinolines towards metal halides in diethyl ether
David Berry Krishna Bukka and Rosemary S. Satchell
pg 89; DOI:
10.1039/P29760000089
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Proton magnetic resonance spectra of amino-acids and peptides relevant to wool structure. Part IV. Relative residence times of dipeptides and tripeptides of phenylalanine and tyrosine
Brian J. Dale and Derry W. Jones
pg 91; DOI:
10.1039/P29760000091
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Trends in the nematic–isotropic liquid transition temperatures for the homologous series of 4-n-alkoxy- and 4-n-alkyl-4-cyanobiphenyls
George W. Gray and Alan Mosley
pg 97; DOI:
10.1039/P29760000097
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Transition state enthalpies of transfer in aqueous dimethyl sulphoxide solutions. The hydroxide-catalysed racemisation of D--methyl--phenylacetophenone
Devendra K. Jaiswal John R. Jones and Richard Fuchs
pg 102; DOI:
10.1039/P29760000102
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Crystal structure of a 1 : 1 complex between silver iodide and morpholine
Gerald B. Ansell
pg 104; DOI:
10.1039/P29760000104
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Stereochemistry of ethyl octahydro-3-methylindolizine-2-carboxylate
John M. Sprake and Keith D. Watson
pg 107; DOI:
10.1039/P29760000107
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X-Ray crystallographic determination of the structure of the p-bromophenylboronate ester of 17,20,21-trihydroxypregn-4-en-3-one
Philip J. Cox Peter D. Cradwick and George A. Sim
pg 110; DOI:
10.1039/P29760000110
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Heterocyclic free radicals. Part VI. Substituent effects on the distribution of the spin density in 10-arylphenoxazine and 10-arylphenothiazine cation radicals
David Clarke Bruce C. Gilbert and Peter Hanson
pg 114; DOI:
10.1039/P29760000114
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Issue 2


Front cover

pg X005; DOI:
10.1039/P297600FX005
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Contents pages

pg P005; DOI:
10.1039/P297600FP005
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Back cover

pg X007; DOI:
10.1039/P297600BX007
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Effects of alkyl chain length on the thermodynamics of proton ionization from arsonic and arsinic acids
Edwin A. Lewis Lee D. Hansen Ernest J. Baca and Don J. Temer
pg 125; DOI:
10.1039/P29760000125
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Application of a Hammett–Taft relation to kinetics of strecker degradation of -amino-acids with phenalene-1,2,3-trione hydrate
William I. Awad Shawky Nashed Saad S. M. Hassan and Rashad F. Zakhary
pg 128; DOI:
10.1039/P29760000128
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Nuclear magnetic resonance spectra of azomethines. Part I. Benzylideneanilines
Adil S. Al-Tai D. Muriel Hall and Andrew R. Mears
pg 133; DOI:
10.1039/P29760000133
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Electron spin resonance study of the interaction between radical ion pairs and macrocyclic polyethers
Gian Franco Pedulli and Angelo Alberti
pg 137; DOI:
10.1039/P29760000137
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Mechanisms of addition. Part II. The stereochemistry of addition of bromine and bromine acetate to some phenyl-substituted olefins
Michael A. Wilson and Paul D. Woodgate
pg 141; DOI:
10.1039/P29760000141
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13C nuclear magnetic resonance studies on aromatic aldehydes. Torsional barriers and conformational equilibria in pyridinecarbaldehydes
Torbjörn Drakenberg
pg 147; DOI:
10.1039/P29760000147
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(Z)- and (E)-3-Alkyldine-1,3-dihydroindol-2-ones : influence of configuration on the transmission of the inductive effect to the carbonyl group
Gianfranco Tacconi Lucia Dacrema Maggi Pierpaolo Righetti Giovanni Desimoni Ornella Azzolina and Victor Ghislandi
pg 150; DOI:
10.1039/P29760000150
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The stabilities of Meisenheimer complexes. Part XI. The effects of ring-size of spiro-complex formation
Michael R. Crampton and Michael J. Willson
pg 155; DOI:
10.1039/P29760000155
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The stabilities of Meisenheimer complexes. Part XII. Some kinetic studies of the reactions of aromatic nitro-compounds with sodium sulphite in water
Michael R. Crampton and Michael J. Willison
pg 160; DOI:
10.1039/P29760000160
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The radical-anion of thioxanthen SS-dioxide and its 9-substituted derivatives
Pierre Lambelet and Edwin A. C. Lucken
pg 164; DOI:
10.1039/P29760000164
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Conformation of hydroxy-L-proline in aqueous solution. Comparison of results from lanthanide ion probe measurements and proton coupling constants
Fuyuhiko Inagaki Mitsuo Tasumi and Tatsuo Miyazawa
pg 167; DOI:
10.1039/P29760000167
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An electron spin resonance study of ring inversion in the radical anions of peri-bridged naphthalenes and singly bridged biphenyls
Gian Franco Pedulli Angelo Alberti Maurizio Guerra Giancarlo Seconi and Piero Vivarelli
pg 173; DOI:
10.1039/P29760000173
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Infrared spectroscopic study of the interaction between 2,6-diarylphenols and alkyl cyanides
Shinichi Ueji Nobuhiko Ueda and Toshio Kinugasa
pg 178; DOI:
10.1039/P29760000178
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Competition between base addition and electron transfer in unsaturated systems: the case of 3-methoxytropone
Crescenzo Festa Lamberto Nucci Francesco Pietra Anna M. Moresco Lucio Pardi and Sergio Santucci
pg 180; DOI:
10.1039/P29760000180
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Nuclear magnetic resonance investigations of carbonium ion intermediates. Part IV. Study of the intermediates involved in the reaction between carboxamides and Lewis acids (extended Vilsmeier reaction) by 1H and 13C nuclear magnetic resonance spectroscopy
Maryvonne L. Martin Gabriel Ricolleau Serge Poignant and Gérard J. Martin
pg 182; DOI:
10.1039/P29760000182
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Conformations of peptides in solution by nuclear magnetic resonance spectroscopy. Part II. Homoallylic coupling in cyclic dipeptides
David B. Davies and Md. Abu Khaled
pg 187; DOI:
10.1039/P29760000187
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Linear free energy relationships. Part VI. Acidity of 4-(5-X-2-hydroxystyryl)-N-methylpyridinium iodides
Harry W. Gibson and F. C. Bailey
pg 196; DOI:
10.1039/P29760000196
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Proton magnetic resonance studies of compounds with bridgehead nitrogen. Part XXIX. Configurational and conformational studies with derivatives of perhydro-oxazolo[4,3-c][1,4]thiazine
Trevor A. Crabb and M. James Hall
pg 203; DOI:
10.1039/P29760000203
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Substituent effects in tautomerism. Part 11. para-Substitution in N-phenylamidines
Michael J. Cook Alan R. Katritzky and Sourena Nadji
pg 211; DOI:
10.1039/P29760000211
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Influence of cosolutes upon the conformation of carbohydrates in aqueous solutions. Part III. Effect of inorganic ions upon the binding of iodine by starch and derivatives of amylose
Terence. J. Painter
pg 215; DOI:
10.1039/P29760000215
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Structure of a 3-aminothiathiophthen : X-ray analysis of 3-amino-2-methylthio-5-phenyl-6a-thiathiophthen {3-amino-2-methylthio-5-phenyl [1,2]dithiolo[1,5-b][1,2]dithiole-7-SIV}
Elma C. Llaguno and Iain C. Paul
pg 228; DOI:
10.1039/P29760000228
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A symmetrically substituted thiathiophthen with unequal sulphur–sulphur bond lengths : crystal and molecular structure of 3,4-diphenyl-6a-thiathiophthen {3,4-diphenyl[1,2]dithiolo[1,5-b][1,2]dithiole-7-SIV}
Paul L. Johnson Elma C. Llaguno and Iain C. Paul
pg 234; DOI:
10.1039/P29760000234
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Structure of an unsymmetrically-substituted thiathiophthen : crystal and molecular structure of 5-methyl-3-[4-methyl-5-(methylthio)thiocarbonyl-2-thienyl]-2-methylthio-6a-thiathiophthen {5-methyl-3-[4methyl-5-(methylthio)thiocarbonyl-2-thienyl]-2-methylthio[1,2]dithiolo[1,5-b][1,2]dithiole-7-SIV}
Elma C. Llaguno Clayton T. Mabuni and Iain C. Paul
pg 239; DOI:
10.1039/P29760000239
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Mechanism of oxidative cleavage by bromine of diazabutadienes (azines) to aldehydes or ketones
Anthony F. Hegarty Joseph A. Kearney Patrick A. Cashell and Francis L. Scott
pg 242; DOI:
10.1039/P29760000242
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A regio- and stereo-selective free radical bromination of steroidal -unsaturated ketones
Vincenzo Calo Luigi Lopez and Giovanni Pesce
pg 247; DOI:
10.1039/P29760000247
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Issue 3


Front cover

pg X009; DOI:
10.1039/P297600FX009
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Contents pages

pg P009; DOI:
10.1039/P297600FP009
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Back cover

pg X011; DOI:
10.1039/P297600BX011
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Crystal and molecular structure of 3-mercapto-1,3-diphenylprop-2-en-1-one by X-ray and neutron diffraction
Leslie F. Power Kenneth E. Turner and Francis H. Moore
pg 249; DOI:
10.1039/P29760000249
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Vinyl carbanions. Part I. Kinetics of hydrogen–deuterium exchange in fluoren-9-ylideneacetonitrile catalysed by sodium ethoxide
B. A. Feit L. Bohor and S. Rubinraut
pg 253; DOI:
10.1039/P29760000253
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New data on keto–enol equilibria of 3-alkylpentane-2,4-diones in aqueous solution
Pierre Alcais and Raymond Brouillard
pg 257; DOI:
10.1039/P29760000257
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Cyclopropa-arenium cations. Part II. Carbon-13 nuclear magnetic resonance spectra of 1-halogenocyclopropabenzenium cations and their 1,1-dihalogeno-precursors
Brian Halton Helmut M. Hügel David P. Kelly Paul Müller and Ulrich Burger
pg 258; DOI:
10.1039/P29760000258
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Crystal structure of the tricyclic diterpene derivative 18-hydroxydecipia-2(4),14-dien-1-oic acid
Edward N. Maslen Peter N. Sheppard Allan H. White and Anthony C. Willis
pg 263; DOI:
10.1039/P29760000263
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Role of addition compounds in the halogenation of benzofurans and benzothiophens
Enrico Baciocchi Sergio Clementi and Giovanni V. Sebastiani
pg 266; DOI:
10.1039/P29760000266
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Crystal structure of acetamidinium chloride
Jack R. Cannon Allan H. White and Anthony C. Willis
pg 271; DOI:
10.1039/P29760000271
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Studies on nitroaromatic compounds. Part VII. A nuclear magnetic resonance study of the reaction of [2H3]methoxide ion with some polynitrodimethylnaphthalenes
Stephen R. Robinson Brian C. Webb and Clifford H. J. Wells
pg 273; DOI:
10.1039/P29760000273
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Photoelectron spectra of the -substituted derivatives of furan, thiophen, selenophen, and tellurophen. A comparative study of the molecular orbital energies
Francesco Fringuelli Gianlorenzo Marino Aldo Taticchi Guiseppe Distefano F. P. Colonna and Salvatore Pignataro
pg 276; DOI:
10.1039/P29760000276
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The mechanism of the gas-phase pyrolysis of esters. Part IV. Effects of substituents at the -carbon atom
Susan de Burgh Norfolk and Roger Taylor
pg 280; DOI:
10.1039/P29760000280
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Inductive and field effects in aromatic substitution. Part VII. Hydrogen-isotope exchange in a bridged anthracene derivative carrying a nitrogen pole
John H. Rees and John H. Ridd
pg 285; DOI:
10.1039/P29760000285
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Inductive and field effects in aromatic substitution. Part VIII. Kinetics of nitration and bromination of the 'onium salts of dithia- and diazacyclophanes
Roberto Danieli Alfredo Ricci and John H. Ridd
pg 290; DOI:
10.1039/P29760000290
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Inductive and field effects in aromatic substitution. Part IX. Assessment of results
John H. Rees John H. Ridd and Alfredo Ricci
pg 294; DOI:
10.1039/P29760000294
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The effect of the terminal trifluoromethyl group on nematic liquid crystal thermal stability
David Coates and George W. Gray
pg 300; DOI:
10.1039/P29760000300
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Crystal structure of anhydrous barium methacrylate
Colin H. L. Kennard Graham Smith Terry M. Greaney and Allan H. White
pg 302; DOI:
10.1039/P29760000302
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The electronic effect of XMe3 and CH2XMe3(X = Si, Ge, Sn, or Pb) substituents in organometallic sulphides. A kinetic and photoelectron spectroscopic study
Francesco Paolo Colonna Roberto Danieli Giuseppe Distefano and Alfredo Ricci
pg 306; DOI:
10.1039/P29760000306
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Acid-catalysed rearrangements in the aryliminoindoline series. Part I. Crystal and molecular structures of 1-ethyl-2-(1-ethyl-2-phenylindol-3yl)-2-phenyl-3-phenyliminoindoline and 1-ethyl-3-(1-ethyl-2-phenylindol-3-yl)-3-phenyl-2-phenyliminoindoline
Martino Colonna Lucedio Greci Leonardo Marchetti Giovanni Dario Andreetti Gabriele Bocelli and Paolo Sgarabotto
pg 309; DOI:
10.1039/P29760000309
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Acid-catalysed rearrangements in the aryliminoindoline series. Part II. Crystal and molecular structure of 2-anilino-3-(1-methyl-2-phenylindol-3-yl)-3-phenyl-3H-indole monohydrate
Martino Colonna Lucedio Greci Leonardo Marchetti Giovanni Dario Andreetti Gabriele Bocelli and Paolo Sgarabotto
pg 317; DOI:
10.1039/P29760000317
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Proton nuclear magnetic resonance studies of protonated cyclopentadithiophenones and cyclopentadithiophens
Peter B. Koster and Matthijs J. Janssen
pg 323; DOI:
10.1039/P29760000323
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Effect of alkyl substituent chain length on the ion-pair dissociation equilibria of quaternary ammonium hexachloroantimonate salts in dichloromethane
Anthony M. Goka and David C. Sherrington
pg 329; DOI:
10.1039/P29760000329
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Crystal and molecular structure of carolenalone, a cycloheptenone sesquiterpene lactone from North Carolina Helenium autumnale L.
Andrew T. McPhail and Kay D. Onan
pg 332; DOI:
10.1039/P29760000332
PDF
Conformational equilibria and barriers to rotation in monohalogenobutanes with methyl substituents. Methyl–halogen interactions. The size of a halogen atom
J. Edgar Anderson Christopher W. Doecke and Harry Pearson
pg 336; DOI:
10.1039/P29760000336
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Crystal structure of syringaresinol
Robert F. Bryan and Lawrence Fallon tert.
pg 341; DOI:
10.1039/P29760000341
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Ring distortions in 2-methyl-2-t-butyl derivatives of 1, 3-dioxan, 1, 3-oxathian, and 1, 3-dithian
Knut Bergesen Brian M. Carden and Michael J. Cook
pg 345; DOI:
10.1039/P29760000345
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Crystal structure of meso-L-glycero-L-gulo-heptitol
Kloy Nimgirawath Veronica J. James and John A. Mills
pg 349; DOI:
10.1039/P29760000349
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Detritiation of diethyl [2-3H1] malonate
John A. Elvidge Devendra K. Jaiswal John R. Jones and Robert Thomas
pg 353; DOI:
10.1039/P29760000353
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Issue 4


Front cover

pg X013; DOI:
10.1039/P297600FX013
PDF
Contents pages

pg P013; DOI:
10.1039/P297600FP013
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Back cover

pg X015; DOI:
10.1039/P297600BX015
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Some observations relating to substituent effects in halogenation. Part VII. The kinetics and reactions of toluene and o- and p-xylene with chlorine acetate in aqueous acetic acid and acetic acid–perchloric acid
Osman M. H. El Dusouqui Abdel Rahman H. El Nadi Mustapha Hassan and Ghariballa Yousif
pg 357; DOI:
10.1039/P29760000357
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Some observations relating to substituent effects in halogenation. Part VIII. The kinetics and reactions of indane, 9,10-dihydroanthracene, and tetralin with chlorine acetate in aqueous acetic acid
Osman M. H. El Dusouqui Mustapha Hassan Abdel Rahman H. El Nadi and Ghariballa Yousif
pg 359; DOI:
10.1039/P29760000359
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Hydrolysis of phenylureas. Part II. Hydrolysis in acid and aqueous solutions
C. Janet Giffney and Charmian J. O'Connor
pg 362; DOI:
10.1039/P29760000362
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Hydrolysis of phenylureas. Part III. Micellar effects on the solubilization and decomposition of 4-methyl- and 4-nitro-phenylurea
Kathryn J. Mollett and Charmian J. O'Connor
pg 369; DOI:
10.1039/P29760000369
PDF
Three-membered rings. Part I. Semiempirical calculations of the molecular conformation of compounds of the type PhCHXCH2(X = CH2, O, S, NH, or CCl2)
Salvatore Sorriso Ferdinanda Stefani Elvio Semprini and Alberto Flamini
pg 374; DOI:
10.1039/P29760000374
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Kinetics and mechanism of a one-step alternative to the Grignard reaction
G. Gordon Cameron and Alan J. S. Milton
pg 378; DOI:
10.1039/P29760000378
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Geometry of the fluorinated cis-decalin system: crystal and molecular structure of cis-perfluorobicyclo[4.4.0]decane-1,6-diol
Margaret Joy Hamor and Thomas A. Hamor
pg 383; DOI:
10.1039/P29760000383
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Kinetics and mechanism of N–H and C–H exchange in pyrrole and indole. Part II. General acid catalysed exchange in aqueous acetonitrile
David M. Muir and Mark C. Whiting
pg 388; DOI:
10.1039/P29760000388
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Interactions of cations with sugar anions. Part II. Crystal structure of strontium 4-O-(4-deoxy--L-threo-hex-4-enosyl)--D-galacturonate–4.5 water
Sheila E. B. Gould Robert O. Gould David A. Rees and Alistair W. Wight
pg 392; DOI:
10.1039/P29760000392
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Relative reactivity of groups bonded to positions 2 and 5 of the thiazole ring
Marcella Bosco Luciano Forlani Paolo E. Todesco and Luigi Troisi
pg 398; DOI:
10.1039/P29760000398
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13C nuclear magnetic resonance studies of some fluorinated and trifluoromethylated aromatic compounds. Studies on 13C–19F coupling constants
David Doddrell Michael Barfield William Adcock Mohammad Aurangzeb and David Jordan
pg 402; DOI:
10.1039/P29760000402
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Crystal, molecular, and electronic structure of an antianxiety agent: 7-chloro-5-(2-chlorophenyl)-1,3-dihydro-3-hydroxy-1,4-benzodiazepin-2-one
Giuliano Bandoli and Dore A. Clemente
pg 413; DOI:
10.1039/P29760000413
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The conformational analysis of perhydropyrido[1,2-c][1,3]oxazines, perhydropyrido[1,2-c][1,3]thiazines, and perhydropyrido[1,2-c] pyrimidines
Ian D. Blackburne Alan R. Katritzky David M. Read Peter J. Chivers and Trevor A. Crabb
pg 418; DOI:
10.1039/P29760000418
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Polyoxamacrobicyclic diamines. Structure of 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane and of its bisborohydride, C18H36N2O62BH3
Bernard Metz Dino Moras and Raymond Weiss
pg 423; DOI:
10.1039/P29760000423
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Molecular conformation and electronic structure. Part III. Crystal and molecular structure of the stable form of N-(p-chlorobenzylidene)-p-chloroaniline
Joel Bernstein and Ilana Izak
pg 429; DOI:
10.1039/P29760000429
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The relative gas-phase proton affinities and polarisabilities of alkyl and silyl ethers
Colin G. Pitt Maurice M. Bursey and Dale A. Chatfield
pg 434; DOI:
10.1039/P29760000434
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Reversible photochemistry, photo-oxidation, and fluorescence of dixanthylidene: temperature and external spin-orbit perturbation effects
Rafi Korenstein Karol A. Muszkat Michael A. Slifkin and Ernst Fischer
pg 438; DOI:
10.1039/P29760000438
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Reactions of allene with amines and active methylene compounds; adduct formation in the presence of nickel complexes
Raymond Baker and Alan H. Cook
pg 443; DOI:
10.1039/P29760000443
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Reactions of allene and aldehydes; adduct formation in the presence of nickel complexes
Raymond Baker and Alan H. Cook
pg 447; DOI:
10.1039/P29760000447
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Dependence of the furan-2-carbaldehyde conformational equilibrium on solvent dielectric constant: direct evidence from pulsed (Fourier transform) nuclear magnetic resonance
Derek J. Chadwick
pg 451; DOI:
10.1039/P29760000451
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Crystal structure of octaethylxanthoporphinogen dihydrate
William S. Sheldrick
pg 453; DOI:
10.1039/P29760000453
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Photorearrangement of quinoline 1-oxides: relevance of ground and excited state basicity and effect of heavy atom quenchers
Gian Gaetano Aloisi and Gianna Favaro
pg 456; DOI:
10.1039/P29760000456
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Crystal and molecular structure of (1S,3S,5R,7S,8R,9R)-9-p-bromo-benzoyloxy-1,4,4,8-tetramethyltricyclo[5.4.0.0]undecane
Andrew Quick and Donald Rogers
pg 460; DOI:
10.1039/P29760000460
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Crystal and molecular structure of parthenolide [4,5-epoxygermacra-1(10),11(13)-dien-12,6-olactone]
Andrew Quick and Donald Rogers
pg 465; DOI:
10.1039/P29760000465
PDF
Kinetic study of homogeneous acid-catalysed oxidation of certain amino-acids by potassium permanganate in moderately concentrated acidic media
Radhey S. Verma Madhusudana J. Reddy and Vyayendra R. Shastry
pg 469; DOI:
10.1039/P29760000469
PDF
Kinetic isotope effects and aliphatic diazo-compounds. Part VII. The decomposition of diazomalonato ions
W. John Albery Christopher W. Conway and John A. Hall
pg 473; DOI:
10.1039/P29760000473
PDF
Crystal and molecular structure of potassium hydrogen norborn-5-ene-2-endo,3-endo-dicarboxylate sesquihydrate, C9H9KO4,1.5H2O
Ferenc Cser and Kálmán Sasvári
pg 478; DOI:
10.1039/P29760000478
PDF

Issue 5


Front cover

pg X017; DOI:
10.1039/P297600FX017
PDF
Contents pages

pg P017; DOI:
10.1039/P297600FP017
PDF
Back cover

pg X019; DOI:
10.1039/P297600BX019
PDF
Structure and conformation of ethyl 6-O-benzoyl-4-iodo-2,3,4-trideoxya--D-hex-2-enopyranoside
Rolf Stokhuyzen and Chung Chieh
pg 481; DOI:
10.1039/P29760000481
PDF
Folded conformations. Part VII. Crystal and molecular structure of NN-[bis-(-tosylbenzyl)] urea acetone solvate. Comparison between solution and solid-state conformation
Rense M. Tel and Jan B. F. N. Engberts
pg 483; DOI:
10.1039/P29760000483
PDF
Deuterium kinetic isotope effect in -elimination from (p-acetylphenethyl)dimethylsulphonium bromide. The influence of added dimethyl sulphoxide
Leonard F. Blackwell
pg 488; DOI:
10.1039/P29760000488
PDF
Reactions of radical anions. Part XVI. Interpretation of the hyperfine coupling constants of 31P nuclei in phosphorus-containing radical anions
Alwyn G. Evans Jeffrey C. Evans and Deri Sheppard
pg 492; DOI:
10.1039/P29760000492
PDF
Comparative behaviour of -complexes in phenylation of 4-methylpyridine by benzoyl peroxide in refluxing benzene
Simone Vidal Jean Court and Jane-Marie Bonnier
pg 497; DOI:
10.1039/P29760000497
PDF
Homolytic abstraction of enolic hydrogen
Alwyn G. Davies and Brenda Muggleton
pg 502; DOI:
10.1039/P29760000502
PDF
Conformation of cis-stilbene and some derivatives studied by nuclear magnetic relaxation measurements
Frank Heatley Michael K. Cox Anne Jones and Brian Jacques
pg 510; DOI:
10.1039/P29760000510
PDF
Crystal structure of the enol form of 1-(4-nitrophenyl)butane-1,3-dione
Raymond D. G. Jones
pg 513; DOI:
10.1039/P29760000513
PDF
Nucleophilic versus general base catalysis in phosphyl (PV) group transfer: application to -chymotrypsin action
Kenneth T. Douglas and Andrew Williams
pg 515; DOI:
10.1039/P29760000515
PDF
Liquid-phase bromination of bromobutane: variation of the ratio of 1,2- to 1,3-dibromobutanes produced
Keith Ody Antony Nechvatal and John M. Tedder
pg 521; DOI:
10.1039/P29760000521
PDF
Structure and reactivity of heterosubstituted nitriles. Part XIV. Kinetics and mechanisms of cyanogen bromide reactions with N-alkylanilines
I. Bacaloglu R. Bacaloglu H. Glatt C. Viragh and G. Ostrogovich
pg 524; DOI:
10.1039/P29760000524
PDF
Crystal and molecular structures of methyl 2,3;4,5-diepoxy-cis-(1H,2H)-bicyclo[4.1.0]heptane-7-carboxylate and methyl 2,5-dihydroxybicyclo[4.1.0]heptane-7-carboxylate
David J. Brauer Carl Krüger and Paul J. Roberts
pg 532; DOI:
10.1039/P29760000532
PDF
Crystal structure of NN-bis-p-bromophenyl-2,2,4,4-tetramethylcyclobutane-1,3-di-imine
Paul Stadel William Jensen James Worman and Robert A. Jacobson
pg 536; DOI:
10.1039/P29760000536
PDF
Preferred molecular conformations of benzoyl(diazo)phenylmethane and 1-benzoyl-1-diazoethane by semiempirical molecular orbital calculations
Salvatore Sorriso and Åse Støgård
pg 538; DOI:
10.1039/P29760000538
PDF
Application of 13C chemical shifts and relaxation times to the study of charge distribution, aggregation, and conformation in carbocyanine dyes. Part I
P. Mark Henrichs
pg 542; DOI:
10.1039/P29760000542
PDF
Ground states of molecules. Part XXXII. A MINDO/3 study of mesoionic oxazoles and imidazoles
Michael J. S. Dewar and Ignatius J. Turchi
pg 548; DOI:
10.1039/P29760000548
PDF
Electron spin resonance detection of radicals RS, RO, and R1 S–R2+ in irradiated solids
Harold C. Box and Edwin E. Budzinski
pg 553; DOI:
10.1039/P29760000553
PDF
Ion-pair aggregation of a long-chain carboxylic acid and an amine in benzene studied by induced circular dichroism
Shunsuke Takenaka Mikiko Sugiyama and Niichiro Tokura
pg 555; DOI:
10.1039/P29760000555
PDF
Electrophilic aromatic substitution. Part XVII. Protiodetritiation of some cycloalkyl- and secondary alkyl-benzenes. A linear free energy relationship for ortho-aromatic substitution
M. M. Jean Le Guen and Roger Taylor
pg 559; DOI:
10.1039/P29760000559
PDF
Steric and electronic effects on self-association of potentially bifunctional catalysts: 4-thiazoline-2-thiones
Emilie Gentric Jacques Lauransan Christian Roussel and Jacques Metzger
pg 565; DOI:
10.1039/P29760000565
PDF
Sensitised photolysis of cis-cyclo-octene vapour
Yoshihisa Inoue Kazuyoshi Moritsugu Setsuo Takamuku and Hiroshi Sakurai
pg 569; DOI:
10.1039/P29760000569
PDF
Dipole moments and absorption spectra of heterocyclic diketones
Vinicio Galasso and Giuseppe C. Pappalardo
pg 574; DOI:
10.1039/P29760000574
PDF
Crystal and molecular structure of eupaformonin, a cytotoxic germacranolide from Eupatorium formosanum HAY
Andrew T. McPhail and Kay D. Onan
pg 578; DOI:
10.1039/P29760000578
PDF
Acylarylnitrosamines. Part IX. Use of benzyne promoters in the conversion of N-nitrosoacetanilide into benzyne
J. I. G. Cadogan Charles D. Murray and John T. Sharp
pg 583; DOI:
10.1039/P29760000583
PDF
Acylarylnitrosamines. Part X. An electron spin resonance spectroscopic investigation of the reactions of aryl radicals with tetraphenylcyclopentadienone and 2,3-diarylindenones : detection of 1-oxo-2,2,3-triphenylindenyl and related radicals and their relevance to dienonepromoted formation of benzyne from benzenediazonium acetate
Elizabeth A. Bell J. I. G. Cadogan Peter W. Milburn Charles D. Murray R. Michael Paton and John T. Sharp
pg 588; DOI:
10.1039/P29760000588
PDF
Studies in decarboxylation. Part VIII. The gas-phase pyrolysis of -acetylenic acids
David B. Bigley and Richard H. Weatherhead
pg 592; DOI:
10.1039/P29760000592
PDF
Reactions over metal catalysts. Part I. The stereochemistry of hydrogenolysis of 3-acetoxynortricyclene
M. Nasseem Akhtar John J. Rooney and W. Roy Jackson
pg 595; DOI:
10.1039/P29760000595
PDF
Infrared examination of rotational isomerism in alkyl furan-2-carboxylates : determination of thermodynamic parameters from infrared data
Derek J. Chadwick John Chambers Robert Macrae G. Denis Meakins and Roger L. Snowden
pg 597; DOI:
10.1039/P29760000597
PDF
Kinetics and mechanism of the Fischer–Hepp rearrangement and denitrosation. Part VII. Reactions at high acidity
Ian D. Biggs and D. Lyn H. Williams
pg 601; DOI:
10.1039/P29760000601
PDF
Dynamic stereochemistry of imines and derivatives. Part VII. Thermal epimerization of chiral oxaziridines
Johannes Bjørgo Derek R. Boyd Rose M. Campbell Norris J. Thompson and W. Brian Jennings
pg 606; DOI:
10.1039/P29760000606
PDF
Dynamic stereochemistry of imines and derivatives. Part VIII. Barriers to rotation around the carbon–nitrogen bond in imine N-oxides (nitrones)
W. Brian Jennings Derek R. Boyd and Lionel C. Waring
pg 610; DOI:
10.1039/P29760000610
PDF
Insecticides. Part V. Crystal structures of -(eeeeee)-1,2,3,4,5,6-hexachlorocyclohexane and -(aaaeee)-1,2,3,4,5,6-hexachlorocyclohexane (lindane)(redeterminations)
Graham Smith Colin H. L. Kennard and Alan H. White
pg 614; DOI:
10.1039/P29760000614
PDF
Tetra-acetylcaffeoylputrescine : an acetyl–cinnamoyl diacylamine. Nuclear magnetic resonance studies of acetyl groups
Roger Davies and Eddie I. Mbadiwe
pg 616; DOI:
10.1039/P29760000616
PDF
Acetolysis of 2,4-dinitrophenyl glycopyranosides
David Cocker and Michael L. Sinnott
pg 618; DOI:
10.1039/P29760000618
PDF

Issue 6


Front cover

pg X021; DOI:
10.1039/P297600FX021
PDF
Contents pages

pg P021; DOI:
10.1039/P297600FP021
PDF
Back cover

pg X023; DOI:
10.1039/P297600BX023
PDF
Theoretical study of charge distribution in the benzoyl and alkynoyl cations
Charles U. Pittman jun. Bong Kim Quock Y. Ng and Lowell D. Kispert
pg 621; DOI:
10.1039/P29760000621
PDF
Crystal structure of 3,3-diacetyl-5,5-dichloro-2,2-dihydroxydiphenylmethane

pg 623; DOI:
10.1039/P29760000623
PDF
Behaviour of nitrile oxides towards nucleophiles. Part II. Substituent effect on the rate of dimerisation of aromatic nitrile oxides to 3,6-diaryl-1,4,2,5-dioxadiazines
Francesco De Sarlo and Antonio Guarna
pg 626; DOI:
10.1039/P29760000626
PDF
Iodine oxidation of arylacetones in alkaline methanol
Yoshio Ogata and Kenji Nagura
pg 628; DOI:
10.1039/P29760000628
PDF
The mechanism of hydrolysis of phosphonium ylides
Andrew Schnell J. Graham Dawber and John C. Tebby
pg 633; DOI:
10.1039/P29760000633
PDF
Study of the thermal decomposition of pentaerythritol tetranitrate
Wee Lam Ng John E. Field and Herman M. Hauser
pg 637; DOI:
10.1039/P29760000637
PDF
Intramolecular catalysis. Part II. Hydrolysis of diphenylmethyl hydrogen phthalate: neighbouring group participation and alkyl–oxygen fission
Malcolm D. Hawkins
pg 639; DOI:
10.1039/P29760000639
PDF
Intramolecular catalysis. Part III. Hydrolysis of 3- and 4-substituted phthalanilic acids [o-(N-phenylcarbamoyl)benzoic acids]
Malcolm D. Hawkins
pg 642; DOI:
10.1039/P29760000642
PDF
Mechanistic investigations in the photochemistry of acyclic conjugated dienes. Significance of the [1,5] sigmatropic shifts of hydrogen
Daniel Rondelez and Stéphane Boué
pg 647; DOI:
10.1039/P29760000647
PDF
The use of spin traps to characterize sulphur- and phosphorus-containing radicals from OO-dialkyl hydrogen phosphorodithioates, zinc bis-(OO-di-isopropyl phosphorodithioate), and related compounds
George Brunton Bruce C. Gilbert and Roger J. Mawby
pg 650; DOI:
10.1039/P29760000650
PDF
Molecular and crystal structure of eupolauramine, a novel type of alkaloid from Eupomatia laurina
Bruce F. Bowden Hans C. Freeman and Raymond D. G. Jones
pg 658; DOI:
10.1039/P29760000658
PDF
Structural effects on the reactivity of carbon radicals in homolytic aromatic substitutions. Part III. Reaction of the 1-adamantyl radical with benzene derivatives
Lorenzo Testaferri Marcello Tiecco Piero Spagnolo Paolo Zanirato and Giorgio Martelli
pg 662; DOI:
10.1039/P29760000662
PDF
Photoreduction of cycloalkanecarbaldehydes
Carel W. Funke and Hans Cerfontain
pg 669; DOI:
10.1039/P29760000669
PDF
General-base-catalysed proton exchange in 1,3-dimethyl-2-iminoimidazolidin-4-one hydriodide
R. Srinivasan and Ross Stewart
pg 674; DOI:
10.1039/P29760000674
PDF
Kinetics of reaction of p-nitrophenyl methyl carbonate with nucleophiles in aqueous solution, and the relative ease of acetyl and methoxycarbonyl transfer reactions
Patricia M. Bond and Roy B. Moodie
pg 679; DOI:
10.1039/P29760000679
PDF
Crystal structure and nuclear magnetic resonance spectra of a 1 : 1 complex of benz[a]anthracene and pyromellitic dianhydride (benzene-1,2,4,5-tetracarboxylic dianhydride)
Roy Foster John Iball Sheelagh N. Scrimgeour and Brent C. Williams
pg 682; DOI:
10.1039/P29760000682
PDF
Proteolytic enzymes: lipophilic binding sites for specific and non-specific substrates of -chymotrypsin
Janos Udris and Andrew Williams
pg 686; DOI:
10.1039/P29760000686
PDF
Kinetics and mechanism of the Fischer–Hepp rearrangement and denitrosation. Part VIII. Substituent effects on denitrosation of aromatic N-nitroso-amines
Ian D. Biggs and D. Lyn H. Williams
pg 691; DOI:
10.1039/P29760000691
PDF
Electrophilic substitution in pyrroles. Part I. Reaction with 4-dimethylaminobenzaldehyde (Ehrlich's reagent) in acid solution
Robert S. Alexander and Anthony R. Butler
pg 696; DOI:
10.1039/P29760000696
PDF
Carbonate pyrolysis. Part IV. The stereochemistry of elimination; a 13C nuclear magnetic resonance study
David B. Bigley Charles Brown and Richard H. Weatherhead
pg 701; DOI:
10.1039/P29760000701
PDF
Studies in decarboxylation. Part IX. The gas-phase pyrolysis of some acids containing two double bonds
David B. Bigley and Richard H. Weatherhead
pg 704; DOI:
10.1039/P29760000704
PDF
Thermodynamic parameters in the conformational equilibria of acetyldiazomethane, 1-acetyl-1-diazoethane, and benzoyl(diazo)phenylmethane using infrared spectroscopy
Giulio Paliani Salvatore Sorriso and Rosario Cataliotti
pg 707; DOI:
10.1039/P29760000707
PDF
Ester linkages in the nematic phase: a thermodynamic study
Michael J. S. Dewar and Anselm C. Griffin
pg 710; DOI:
10.1039/P29760000710
PDF
Terminal groups in the nematic and cholesteric phases: a thermodynamic study
Michael J. S. Dewar and Anselm C. Griffin
pg 713; DOI:
10.1039/P29760000713
PDF
Crystal structure of (+)-isomenthyl p-bromophenylcarbamate and absolute configuration and conformation of isomenthol by X-ray diffraction and nuclear magnetic resonance studies
Gopinath Kartha Kuan Tee Go Ajay K. Bose and M. S. Tibbetts
pg 717; DOI:
10.1039/P29760000717
PDF
Proteolytic enzymes: electrophilic participation in the acylation step
Hilary C. Hawkins and Andrew Williams
pg 723; DOI:
10.1039/P29760000723
PDF
1H and 13C nuclear magnetic resonance spectra of benzylidenemalononitriles : a method for the determination of + substituent constants
Tamar B. Posner and C. Dennis Hall
pg 729; DOI:
10.1039/P29760000729
PDF
Formation of Baudisch complexes [FeII(CN)5,RNO]3– from alkyl- and aryl-hydroxylamines and aquapentacyanoferrate(3–) anions, [FeII(CN)5,H2O]3–
William A. Waters
pg 732; DOI:
10.1039/P29760000732
PDF
13C–H coupling constants as a tool in tautomerism studies of 1,2,3-triazole, 1,2,4-triazole, and tetrazole
Mikael Begtrup
pg 736; DOI:
10.1039/P29760000736
PDF
Amine oxidation. Part X. The oxidation of some 4-substituted NN-dimethylbenzylamines and a selection of other amines with 1-chlorobenzotriazole
John R. Lindsay Smith and John S. Sadd
pg 741; DOI:
10.1039/P29760000741
PDF
Linear free energy ortho-correlations in the thiophen series. Part II. Acid dissociation of some 3-substituted thiophen-2-carboxylic acids in water
Domenico Spinelli Renato Noto and Giovanni Consiglio
pg 747; DOI:
10.1039/P29760000747
PDF
Conformational equilibria in cis-C-methyldecahydroquinolines: studies at low temperature using 13C and 1H magnetic resonance spectroscopy
Harold Booth D. Vaughan Griffiths and Mary L. Jozefowicz
pg 751; DOI:
10.1039/P29760000751
PDF
Evaluation of the equilibrium and activation parameters for the interconversion of the conformational isomers of some N-acylprolines by nuclear magnetic resonance spectroscopy
Hernani L. Maia Keith G. Orrell and H. N. Rydon
pg 761; DOI:
10.1039/P29760000761
PDF
Photoelectron spectra of molecules. Part VII. Cyclopropylallenes
M. J. S. Dewar G. J. Fonken T. B. Jones and David E. Minter
pg 764; DOI:
10.1039/P29760000764
PDF
Crystal and molecular structure of N-acetyl- L -glutamine
Mathur R. Narasimhamurthy Kailasam Venkatesan and Fritz Winkler
pg 768; DOI:
10.1039/P29760000768
PDF
Catalysis of ester hydrolysis by cationic micelles of surfactants containing the imidazole ring
Umberto Tonellato
pg 771; DOI:
10.1039/P29760000771
PDF

Issue 7


Front cover

pg X025; DOI:
10.1039/P297600FX025
PDF
Contents pages

pg P025; DOI:
10.1039/P297600FP025
PDF
Back cover

pg X027; DOI:
10.1039/P297600BX027
PDF
Electron spin resonance spectra of some substituted methyl radicals
Edwin A. C. Lucken and Bruno Poncioni
pg 777; DOI:
10.1039/P29760000777
PDF
Kinetics and mechanism of the alkaline hydrolysis of guanidine, hexamethylguanidinium perchlorate, and tetramethylurea
Roger B. Homer and Kuruwitagae W. Alwis
pg 781; DOI:
10.1039/P29760000781
PDF
The kinetics and mechanisms of aromatic halogen substitution. Part XXXII. The directive power of the acetoxy-group
Peter B. D. de la Mare Neil S. Isaacs and Michael J. McGlone
pg 784; DOI:
10.1039/P29760000784
PDF
Herbicides. Part I. Crystal structure of 2,4-D (2,4-dichlorophenoxyacetic acid)
Graham Smith Colin H. L. Kennard and Alan H. White
pg 791; DOI:
10.1039/P29760000791
PDF
Optically active nine-membered rings incorporating the 8- and 8-positions of 1,1-binaphthyl
Margaret M. Harris and Shyam Singh
pg 793; DOI:
10.1039/P29760000793
PDF
Acaricides. Part I. Crystal structure of Pentac [synclinal 1,1,2,2,3,3,4,4,5,5-decachloro-1,1-bis(cyclopenta-2,4-dienyl)]
Graham Smith Kelvin G. Shields and Colin H. L. Kennard
pg 796; DOI:
10.1039/P29760000796
PDF
Pyrolysis of t-butyl N-arylcarbamates in the gas phase, and correlation of the elimination rates with those obtained in solution
Roger Taylor and Melanie P. Thorne
pg 799; DOI:
10.1039/P29760000799
PDF
Sulphone structures. Part III. Crystal and molecular structure of 5,5-dichloro-2-hydroxy-2-(phenylsulphonyl)azoxybenzene
T. Stanley Cameron Robert J. Cummings and Anthony C. Knipe
pg 802; DOI:
10.1039/P29760000802
PDF
Conformations of 3,5-dichloroanisole and 3,5-dibromoacetophenone determined from 1H nuclear magnetic resonance spectra of nematic solutions
James W. Emsley John C. Lindon and Joan M. Street
pg 805; DOI:
10.1039/P29760000805
PDF
Configurational effects in the -scission of phosphoranyl radicals
John W. Cooper and Brian P. Roberts
pg 808; DOI:
10.1039/P29760000808
PDF
Cholesteryl myristate: structures of the crystalline solid and mesophases
Bryan M. Craven and George T. DeTitta
pg 814; DOI:
10.1039/P29760000814
PDF
Crystal and molecular structure of 4,10-dibromo-1,7-methano[12]annulene
Angelo Mugnoli and Massimo Simonetta
pg 822; DOI:
10.1039/P29760000822
PDF
The gas-phase photolysis of cyclobutanecarbaldehyde
Carel W. Funke and Hans Cerfontain
pg 826; DOI:
10.1039/P29760000826
PDF
Reaction of dinitrogen trioxide with 2-methylpropene and other alkenes. Evidence for electrophilic nitrosation
James R. Park and D. Lyn H. Williams
pg 828; DOI:
10.1039/P29760000828
PDF
Mechanistic studies in the chemistry of urea. Part I. Reaction with pentane-2,4-dione (acetylacetone)
Anthony R. Butler and Elizabeth Leitch
pg 832; DOI:
10.1039/P29760000832
PDF
The suggested role of partial dislocations in the single crystal single crystal phase transition of a cyclo-octane molecular cationic salt
Gordon M. Parkinson John M. Thomas John O. Williams Michael J. Goringe and Linn W. Hobbs
pg 836; DOI:
10.1039/P29760000836
PDF
Effect of 4-t-butyl and other 4-substituents on rate constants for reactions of 1,1-disubstituted cyclohexanes and piperidines. 4-t-Butyl derivatives as valid reactivity models in the kinetic method of conformational analysis of cyclohexanes
David R. Brown Philip G. Leviston James McKenna Jean M. McKenna Raymond A. Melia John C. Pratt and Barrie G. Hutley
pg 838; DOI:
10.1039/P29760000838
PDF
Laser Raman spectra of some non-conjugated steroid olefins
J. Eric D. Davies Philip Hodge and Munir N. Khan
pg 841; DOI:
10.1039/P29760000841
PDF
Inductive effect in the relative fluorescence quantum yields of oxybarbiturates
Leslie A. King
pg 844; DOI:
10.1039/P29760000844
PDF
The acidities of weak acids. Part IV. Some methyl styryl ketones
Suheila T. Hamdi John R. Jones and Trevor G. Rumney
pg 846; DOI:
10.1039/P29760000846
PDF
The separation of polar and steric effects. Part XIII. Kinetics of the reactions of cinnamic acid and meta-substituted cinnamic acids with diazodiphenylmethane in various alcohols and in aprotic solvents
Norman B. Chapman David J. Newman John Shorter and H. Michael Wall
pg 847; DOI:
10.1039/P29760000847
PDF
Homoallylic coupling in 1,4-dihydronaphthalenes
Martin C. Grossel and Rodney C. Hayward
pg 851; DOI:
10.1039/P29760000851
PDF
Decomposition of hydroperoxides by boric acid anhydride in solution. Electrophilic hydroxylation of the solvent
Hiroshi Sakaguchi Etsuo Niki and Yoshio Kamiya
pg 855; DOI:
10.1039/P29760000855
PDF
Study of bipyridyl radical cations. Part III. Reaction of paraquat radical cation with oxygen and with chromic ions in methanol
Alwyn G. Evans Neil K. Dodson and Norman H. Rees
pg 859; DOI:
10.1039/P29760000859
PDF
Properties of the liquid crystals formed by some 4-substituted 4-(-p-substituted arylethyl)biphenyls
David Coates and George W. Gray
pg 863; DOI:
10.1039/P29760000863
PDF

Issue 8


Front cover

pg X029; DOI:
10.1039/P297600FX029
PDF
Contents pages

pg P029; DOI:
10.1039/P297600FP029
PDF
Back cover

pg X031; DOI:
10.1039/P297600BX031
PDF
Photochemical and photophysical behaviour of benzoylpyridines. Part I. Triplet–triplet energy transfer to biacetyl
Gianna Favaro
pg 869; DOI:
10.1039/P29760000869
PDF
Extrathermodynamic relationships for ion-pair equilibria in media of low dielectric constant
Geoffrey C. Greenacre and Ronald N. Young
pg 874; DOI:
10.1039/P29760000874
PDF
trans: cis Olefin ratios in the elimination reactions of 1-benzylethyl halides and toluene-p-sulphonate in different base–solvent systems
Sergio Alunni and Enrico Baciocchi
pg 877; DOI:
10.1039/P29760000877
PDF
Electro-organic reactions. Part VI. Stereoselective cathodic reduction of unhindered cyclic ketones
James P. Coleman Richard J. Holman and James H. P. Utley
pg 879; DOI:
10.1039/P29760000879
PDF
Electro-organic reactions. Part VII. The cathodic reduction of carvomenthone, menthone, and camphor
Richard J. Holman and James H. P. Utley
pg 884; DOI:
10.1039/P29760000884
PDF
Alkaline hydrolysis of aryl phosphoramidates and their cyclic analogues
Charles Brown James A. Boudreau Barry Hewitson and Robert F. Hudson
pg 888; DOI:
10.1039/P29760000888
PDF
The application of low temperature 13C nuclear magnetic resonance spectroscopy to the determination of the A values of amino-, methylamino-, and dimethylamino-substituents in cyclohexane
Harold Booth and Mary L. Jozefowicz
pg 895; DOI:
10.1039/P29760000895
PDF
The stabilities of Meisenheimer complexes. Part XIII. Kinetic and equilibrium data for spiro-complex formation from 1-(2-mercaptoethylthio)- and 1-(2-hydroxyethylthio)-2,4,6-trinitrobenzene in water
Michael R. Crampton and Michael J. Willison
pg 901; DOI:
10.1039/P29760000901
PDF
Substituent effects in five-membered rings: Het constants for thia- and oxa-substituents from the reaction of arenesulphonyl chlorides with aniline
Emanuele Maccarone Giuseppe Musumarra and Gaetano A. Tomaselli
pg 906; DOI:
10.1039/P29760000906
PDF
Unstable intermediates. Part CLXIII. Methyl radical anion adducts: radiation effects on dimethyl sulphoxide, dimethyl sulphone, and their solutions in water and methanol
Martyn C. R. Symons
pg 908; DOI:
10.1039/P29760000908
PDF
Photodecarboxylation of carboxylic acids sensitized by triplet benzophenone and duroquinone. A flash photolysis electron spin resonance and chemically induced dynamic nuclear polarization nuclear magnetic resonance investigation
P. R. Bowers K. A. McLauchlan and R. C. Sealy
pg 915; DOI:
10.1039/P29760000915
PDF
Fragmentation paths of hydrazonyl halides upon electron impact; simulation of nitrilimine formation
Peder Wolkoff
pg 921; DOI:
10.1039/P29760000921
PDF
Aromatic reactivity. Part LXI. Reactivities and solvent isotope effects in the base cleavage of triorgano-silicon, -germanium, and -tin groups from furan, thiophen, benzofuran, and benzothiophen rings
Colin Eaborn and Giancarlo Seconi
pg 925; DOI:
10.1039/P29760000925
PDF
Aqueous dissociation of dihydroxycyclopropenone (deltic acid)
Robert I. Geib and Lowell M. Schwartz
pg 930; DOI:
10.1039/P29760000930
PDF
The carbanion mechanism of olefin-forming elimination. Part VII. The isotope effect maximum in the dehydrochlorination of 2,2,2-trichloro-1,1-bis-(p-chlorophenyl)ethane by various bases in alcholic solvents
Duncan J. McLennan
pg 932; DOI:
10.1039/P29760000932
PDF
Kinetics and mechanism of the acetate catalysed hydrolysis of 4-methoxyphenyl chloroformate and 4-methoxyphenyl fluoroformate in aqueous dioxan. Evidence for rate-determining attack of acetate ions on an intermediate mixed anhydride
Alan Queen and Takla A. Nour
pg 935; DOI:
10.1039/P29760000935
PDF
Mechanism of the permanganate oxidation of unsaturated compounds. Part VI. Kinetic investigation of the oxidation of methylmaleic acid, methylfumaric acid, and dimethylmaleic acid
Miklós Jáky and László I. Simándi
pg 939; DOI:
10.1039/P29760000939
PDF
Steric effects in five-membered rings. Part VI. Kinetics of oxidation of -substituted cyclopentanols by chromium(VI) oxide
Pablo S. Wechsler and Benzion Fuchs
pg 943; DOI:
10.1039/P29760000943
PDF
Intramolecular cation exchange in ion pairs. Part II. Isomeric radical ion pairs of dithiolactones
Gian Franco Pedulli Paolo Zanirato Angelo Alberti Maurizio Guerra and Marcello Tiecco
pg 946; DOI:
10.1039/P29760000946
PDF
Correlation of configuration of some organosilanes
Arthur Holt and Michael J. Smith
pg 952; DOI:
10.1039/P29760000952
PDF
Epimerization of an optically active hexaco-ordinated phosphorus compound: kinetic studies
Max Koenig Alain Klaébé Aurelio Munoz and Robert Wolf
pg 955; DOI:
10.1039/P29760000955
PDF
Steroid–acid colour reactions. Part I. Carbon-13 nuclear magnetic resonance spectra of various protonated aliphatic ketones and their pKBH+ values
Anthony R. Butler
pg 959; DOI:
10.1039/P29760000959
PDF
Steroid–acid colour reactions. Part II. Carbon-13 nuclear magnetic resonance and ultraviolet spectra of protonated androst-4-ene-3,17-dione, pregn-4-ene-3, 20-dione, and androst-4-ene-3,11,17-trione
Anthony R. Butler and Howard A. Jones
pg 963; DOI:
10.1039/P29760000963
PDF
Intermediates in the decomposition of aliphatic diazo-compounds. Part XII. Chemically induced dynamic polarisation of fluorine-19 and proton nuclei in the insertion of diarylmethylenes into benzyl fluoride
Donald Bethell Max R. Brinkman John Hayes and Kenneth McDonald
pg 966; DOI:
10.1039/P29760000966
PDF
Crystal and molecular structure of 6,7,9,10,12,13,20,21,23,24,26,27-dodecahydrodibenzo[b,n][1,4,7,10,13,16,19,22]octaoxacyclotetracosin (dibenzo-24-crown-8)
Ian R. Hanson David L. Hughes and Mary R. Truter
pg 972; DOI:
10.1039/P29760000972
PDF

Issue 9


Front cover

pg X033; DOI:
10.1039/P297600FX033
PDF
Contents pages

pg P033; DOI:
10.1039/P297600FP033
PDF
Back cover

pg X035; DOI:
10.1039/P297600BX035
PDF
Indirect 13C–1H coupling in asymmetrically trisubstituted benzenes: a carbon-13 nuclear magnetic resonance study
Friedrich von Massow and Martin A. R. Smith
pg 977; DOI:
10.1039/P29760000977
PDF
Nucleophilic ion pairs. Part II. Micellar catalysis of proton abstraction by hydroxamate anions
Seiji Shinkai and Toyoki Kunitake
pg 980; DOI:
10.1039/P29760000980
PDF
The thermal decomposition of propanoic and 2-methylpropanoic anhydrides in the gas phase
Peter G. Blake Alan Craggs and Mohammad Baghal Vayjooee
pg 986; DOI:
10.1039/P29760000986
PDF
Reactions of keten. Part V. Gas-phase reactions with carboxylic acids. Effect of alkyl substituents
Peter G. Blake and Mohammad Baghal Vayjooee
pg 988; DOI:
10.1039/P29760000988
PDF
Sesquiterpenoids. Part XXII. X-Ray crystallographic determination of the stereochemistry and conformation of deacetylneotenulin
Philip J. Cox and George A. Sim
pg 990; DOI:
10.1039/P29760000990
PDF
Kinetics of the hydrochloric acid-catalysed hydrolyses of benzoic anhydrides in various dioxan–water mixtures
Giuseppe Calvaruso F. Paolo Cavasino and Emanuele Di Dio
pg 993; DOI:
10.1039/P29760000993
PDF
Nucleophilic substitution in -halogeno-sulphoxides. Part II. Dependence of the reaction mechanism on structural factors and on the nature of nucleophile
Mauro Cinquini Stefano Colonna Dario Landini and Angela Maria Maia
pg 996; DOI:
10.1039/P29760000996
PDF
Cleavage of carbon–oxygen single bonds in the reaction of aryl ethyl acetals with ethylmagnesium bromide in diethyl ether. A kinetic study
Paolo Beltrame Gioanna Gelli and Aldo Loi
pg 1001; DOI:
10.1039/P29760001001
PDF
X-Ray crystal structure conformational studies on r-4,c-6-dimethyl-1,3-dithian and its oxides, r-4,c-6-dimethyi-1,3-dithian t-1 -oxide, and r-4,c-6-dimethyl-1,3-dithian t-1,t-3-dioxide
Andrew T. McPhail Kay D. Onan and Jorma Koskimies
pg 1004; DOI:
10.1039/P29760001004
PDF
Kinetics and mechanism of base catalysed hydrolysis of barbituric acid
M. Niyaz Khan and A. Aziz Khan
pg 1009; DOI:
10.1039/P29760001009
PDF
Electron spin resonance of -ray induced radicals in thiourea–adamantane solid solutions
A. Faucitano A. Buttafava and F. Faucitano Martinotti
pg 1014; DOI:
10.1039/P29760001014
PDF
Electron spin resonance study of radicals in -irradiated mono- and poly-cyclic olefins. Part III. Allyl and pentadienyl radicals from dienes and trienes with strained ring structures
A. Faucitano A. Buttafava F. Faucitano Martinotti and S. Cesca
pg 1017; DOI:
10.1039/P29760001017
PDF
Mechanism of the cyanide ion-catalysed cleavage of benzils by amines in aqueous dioxan
Yoshiro Ogata Atsushi Kawasaki and Ken'ichi Akutagawa
pg 1021; DOI:
10.1039/P29760001021
PDF
The carbon-13 nuclear magnetic resonance spectra of the antibiotic polyacetylenic nitrile, diatretyne 2 (7-cyanohept-trans-2-ene-4,6-diynoic acid), and related compounds
Milton T. W. Hearn and John L. Turner
pg 1027; DOI:
10.1039/P29760001027
PDF
1,3-Dipolar cycloaddition of mesitonitrile oxide to cis- and trans-cyclo-octene. A kinetic investigation
Giorgio Bianchi and Domenico Maggi
pg 1030; DOI:
10.1039/P29760001030
PDF
Enthalpy of formation of phenyl formate and related bond dissociation energies
Martin E. Anthoney A. Selwood Carson and Peter G. Laye
pg 1032; DOI:
10.1039/P29760001032
PDF
Stereochemistry of hydroximic acid derivatives. Crystal and molecular structure of N-phenyl-2,6-dichlorobenzamide oxime
Alessandro Dondoni Gastone Gilli and Michele Sacerdoti
pg 1036; DOI:
10.1039/P29760001036
PDF
Electron spin resonance studies. Part XLVIII. Radicals derived from organic sulphites and related compounds
Bruce C. Gilbert Hugh A. H. Laue Richard O. C. Norman and Roger C. Sealy
pg 1040; DOI:
10.1039/P29760001040
PDF
Electron spin resonance studies. Part IL. Radicals derived from oxirans in aqueous solution
Anthony J. Dobbs Bruce C. Gilbert Hugh A. H. Laue and Richard O. C. Norman
pg 1044; DOI:
10.1039/P29760001044
PDF
Electron spin resonance studies. Part L. Reactions of alkoxyl radicals generated from alkyl hydroperoxides and titanium(III) ion in aqueous solution
Bruce C. Gilbert Robert G. G. Holmes Hugh A. H. Laue and Richard O. C. Norman
pg 1047; DOI:
10.1039/P29760001047
PDF
Dynamic nuclear magnetic resonance investigation of phosphonamidothioic and phosphonamidous chlorides
James Burdon Jacqueline C. Hotchkiss and W. Brian Jennings
pg 1052; DOI:
10.1039/P29760001052
PDF
Quantitative aspects of Lewis acidity. Part XVI. Acidity of covalent metal halides towards substituted anilines in dioxan. The validity of H0 as a measure of Lewis acid strength
Krishna Bukka and Rosemary S. Satchell
pg 1058; DOI:
10.1039/P29760001058
PDF
Kinetics of the hydrolysis of thioacetamide in alkaline solution
Oswald M. Pesters and Camiel J. De Ranter
pg 1062; DOI:
10.1039/P29760001062
PDF
Cyclisation of unsaturated phosphoranyl radicals
Alwyn G. Davies Maxwell J. Parrott and Brian P. Roberts
pg 1066; DOI:
10.1039/P29760001066
PDF
Reversible hydrogen photoabstraction by nitroaromatic compounds. A chemically induced nuclear polarization study
Karol A. Muszkat and Meir Weinstein
pg 1072; DOI:
10.1039/P29760001072
PDF
Polyelectrolyte catalysis of the alkaline hydrolysis of neutral and anionic esters
Hiromi Kitano Masahiro Tanaka and Tsuneo Okubo
pg 1074; DOI:
10.1039/P29760001074
PDF
Theoretical studies of aromatic substitution. Part II. Gas-phase protonation of benzene and toluene
J. T. Gleghorn and F. W. McConkey
pg 1078; DOI:
10.1039/P29760001078
PDF
The photochemistry of some cycloalkanecarbaldehydes in inert solvents
Carol W. Funke Jan L. M. de Boer Jan A. J. Geenevasen and Hans Cerfontain
pg 1083; DOI:
10.1039/P29760001083
PDF
Electrophilic aromatic substitution. Part XV. The kinetics, mechanism, and products of nitrodebromination in sulphuric acid
Roy B. Moodie Kenneth Schofield and John B. Weston
pg 1089; DOI:
10.1039/P29760001089
PDF

Issue 10


Front cover

pg X037; DOI:
10.1039/P297600FX037
PDF
Contents pages

pg P037; DOI:
10.1039/P297600FP037
PDF
Back cover

pg X039; DOI:
10.1039/P297600BX039
PDF
Crystal and molecular structure of NN-dimethyldiphenylphosphinamide

pg 1101; DOI:
10.1039/P29760001101
PDF
Synthesis and spectroscopic properties of 1,4-diarylbutenynes
Alois H. A. Tinnemans and Wim H. Laarhoven
pg 1104; DOI:
10.1039/P29760001104
PDF
Photocyclisations of 1,4-diarylbut-1-en-3-ynes. Part II. Mechanism of the reaction
Alois H. A. Tinnemans and Wim H. Laarhoven
pg 1111; DOI:
10.1039/P29760001111
PDF
Photocyclisations of 1,4-diarylbut-1-en-3-ynes. Part III. Scope and limitations of the reaction
Alois H. A. Tinnemans and Wim H. Laarhoven
pg 1115; DOI:
10.1039/P29760001115
PDF
Conformational studies by dynamic nuclear magnetic resonance. Part III. Rotamers arising from restricted motion in substituted benzaldehydes
Lodovico Lunazzi Antonello Ticca Dante Macciantelli and Giuseppe Spunta
pg 1121; DOI:
10.1039/P29760001121
PDF
Crystal structure, and infrared and proton magnetic resonance spectra of 3-cyanomethylsulphonyl-2-morpholinocyclohexene : evidence for a C–H N intramolecular hydrogen bond
Michael P. Sammes Richard L. Harlow and Stanley H. Simonsen
pg 1126; DOI:
10.1039/P29760001126
PDF
Intramolecular hydrogen bonds involving polar carbon–hydrogen bonds: infrared and 1H nuclear magnetic resonance spectra of some cyanomethyl and benzyl sulphones
Michael P. Sammes and Richard L. Harlow
pg 1130; DOI:
10.1039/P29760001130
PDF
Reactivity of thieno[2,3-b] pyridine towards electrophilic substitution
Sergio Alunni Sergio Clementi and LeRoy H. Klemm
pg 1135; DOI:
10.1039/P29760001135
PDF
Crystal and molecular structure of an OH hydrogen-bonded system : 2,2-bis-(2-hydroxy-5-methyl-3-t-butylphenyl)propane
Andrew D. U. Hardy and David D. MacNicol
pg 1140; DOI:
10.1039/P29760001140
PDF
Rotational isomerism. Part XX. Relative conformational stabilities of some chlorofluoropropanes
Raymond J. Abraham and Philip Loftus
pg 1142; DOI:
10.1039/P29760001142
PDF
Group IVB organometal derivatives of pyridine. Part II. The reaction with bis(trimethylsilyl)mercury; organometal-substituted N-trimethylsilylpyridyl free radicals
Terence N. Mitchell
pg 1149; DOI:
10.1039/P29760001149
PDF
An electron spin resonance study of phosphoranyl radicals derived from tetra-alkyl esters of phosphorous phosphoric anhydride (RO)2POP(O)(OR)2
Alwyn G. Davies Maxwell J. Parrott Brian P. Roberts and Aleksandra Skowronska
pg 1154; DOI:
10.1039/P29760001154
PDF
Allylic carbonium ions. Part I. Acetolysis of 1,1- and 3,3-dimethylallyl 2,4-dinitrophenyl ether
K. Brian Astin and Mark C. Whiting
pg 1157; DOI:
10.1039/P29760001157
PDF
Allylic carbonium ions. Part II. Solvolysis and cyclisation of some monoterpene 2,4-dinitrophenyl ethers
K. Brian Astin and Mark C. Whiting
pg 1160; DOI:
10.1039/P29760001160
PDF
Reactions of radical anions. Part XVII. The reactions of triphenylphosphine oxide with alkali metals in ethereal solvents
Alwyn G. Evans Jeffrey C. Evans and Deri Sheppard
pg 1166; DOI:
10.1039/P29760001166
PDF
Crystal structure of a clathrate inclusion compound of hydroquinone and hydrogen sulphide
Thomas C. W. Mak John S. Tse Chi-Sang Tse Ka-Sing Lee and Yuet-Han Chong
pg 1169; DOI:
10.1039/P29760001169
PDF
Amine oxidation. Part XI. Oxidation of some substituted tertiary alkylamines and some NN-dimethylphenethylamines with potassium hexacyanoferrate(III)
John R. Lindsay Smith and Leonard A. V. Mead
pg 1172; DOI:
10.1039/P29760001172
PDF
Kinetics of reactions in heterocycles. Part XV. Reactions of 2-, 6-, or 8-methylthio-1-, -3-, -7-, or -9-methylpurines and related compounds with methoxide ions in methanol
Rodney J. Badger and Gordon B. Barlin
pg 1176; DOI:
10.1039/P29760001176
PDF
Anodic oxidation of carboxamides. Part II. Anodic oxidation and pyridination of N-methyl-4-methoxybenzanilide in acetonitrile
Masaichiro Masui Hidenobu Ohmori Hiroteru Sayo Ayako Ueda and Chihiro Ueda
pg 1180; DOI:
10.1039/P29760001180
PDF
Kinetics and mechanism of addition of acids to olefins. Part I. Addition of acetic acid to cyclic and strained bicyclic olefins catalysed by trifluoromethanesulphonic acid
Roger M. G. Roberts
pg 1183; DOI:
10.1039/P29760001183
PDF
Proton magnetic resonance spectra of amino-acids and peptides relevant to wool structure. Part VI. Relative residence times of peptides of histidine, tryptophan, and valine
Brian J. Dale and Derry W. Jones
pg 1190; DOI:
10.1039/P29760001190
PDF

Issue 11


Front cover

pg X041; DOI:
10.1039/P297600FX041
PDF
Contents pages

pg P041; DOI:
10.1039/P297600FP041
PDF
Back cover

pg X043; DOI:
10.1039/P297600BX043
PDF
Ab initio Gaussian calculations on the CH3 and CH2F cations
James Burdon D. W. Davies and Guillermo del Conde
pg 1193; DOI:
10.1039/P29760001193
PDF
Medium-sized cyclophanes. Part XVIII. Iodine-induced cycloisomerization of methyl-, ethyl-, and isopropyl-[2.2]metacyclophanes. -Basicity and additional strain energy terms as controlling factors
Takeo Sato and Tetsuo Takemura
pg 1195; DOI:
10.1039/P29760001195
PDF
Stabilization of singlet ethoxycarbonylnitrene by 1,4-dioxan
Hiroshi Takeuchi Kazunori Kinoshita Syed Mohammad Abdul-Hai Michiharu Mitani Teruko Tsuchida and Kikuhiko Koyama
pg 1201; DOI:
10.1039/P29760001201
PDF
Direct carbon-13 nuclear magnetic resonance study of boron trifluoride complexes with alkyl and cyclic ketones
Anthony Fratiello Robert Kubo and Stanley Chow
pg 1205; DOI:
10.1039/P29760001205
PDF
Reaction of phosphonated acetals. Acid-catalysed hydrolysis of dialkyl 2,2-dialkoxyethylphosphonates
Mordehai Halmann David Vofsi and Shaul Yanai
pg 1210; DOI:
10.1039/P29760001210
PDF
Crystal and molecular structure of cis-2,trans-3-dibromo-cis-4-t-butyl-cyclohexyl p-nitrobenzoate: a case of non-chair conformation of a saturated monocyclic cyclohexane derivative
Giuseppe Bellucci Giancarlo Berti Marcello Colapietro Riccardo Spagna and Luigi Zambonelli
pg 1213; DOI:
10.1039/P29760001213
PDF
Crystal structure and relative configuration of ()-11,12-dihydroglaziovine. Stereochemistry of reduced proaporphines
Arturo Colombo
pg 1218; DOI:
10.1039/P29760001218
PDF
Homodesmotic reactions for the assessment of stabilization energies in benzenoid and other conjugated cyclic hydrocarbons
Philip George Mendel Trachtman Charles W. Bock and Alistair M. Brett
pg 1222; DOI:
10.1039/P29760001222
PDF
Stereochemisty. Part III. Conformation of eight-membered heterocyclic rings. Conformation of NN-diphenyl-3,7-diaza-1,5-dithiacyclo-octane in dioxan solution
M. Vivekananda Bhatt Shiravante Atmaram and Vuppalapatty Baliah
pg 1228; DOI:
10.1039/P29760001228
PDF
Structure of gaseous C2H4O2+ ions formed by McLafferty rearrangement from aliphatic acids
Karsten Levsen and Helmut Schwarz
pg 1231; DOI:
10.1039/P29760001231
PDF
Molecular conformation of di-2-pyridyl sulphide. A dipole moment, 1H nuclear magnetic resonance, and CNDO/2 study
Claude Chachaty Giuseppe C. Pappalardo and Giuseppe Scarlata
pg 1234; DOI:
10.1039/P29760001234
PDF
Conformations of peptides in solution by nuclear magnetic resonance spectroscopy. Part III. Cyclic dipeptide ring conformations
David B. Davies and Md. A. Khaled
pg 1238; DOI:
10.1039/P29760001238
PDF
N-oxides and related compounds. Part XLVI. Chemical and physical properties of pyridine 1-nitroimides and comparison with quantum chemical predictions
Jean Arriau Alain Dargelos Jan Epsztajn Alan R. Katritzky Edward Lunt James W. Mitchell S. Q. Abbas Rizvi and Gilberto Roch
pg 1245; DOI:
10.1039/P29760001245
PDF
Photochemistry of -disbstituted azoalkanes. Part II. Photolytic dechlorination, decomposition, and oxidation of -dichloro- and -diacyloxy-azoalkanes
Nissim Levi and Donald S. Malament
pg 1249; DOI:
10.1039/P29760001249
PDF
Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
Norma Sbarbati Nudelman and Dionisio Garrido
pg 1256; DOI:
10.1039/P29760001256
PDF
-Styrylcobaloximes: mechanism of formation from -styryl halides and mechanism of cleavage by electrophiles
David Dodd Michael D. Johnson B. Spencer Meeks David M. Titchmarsh K. Nguyen Van Duong and Alain Gaudemer
pg 1261; DOI:
10.1039/P29760001261
PDF
An e.s.r. investigation of radical reactions of some sulphur-containing phenolic antioxidants
George Brunton Bruce C. Gilbert and Roger J. Mawby
pg 1267; DOI:
10.1039/P29760001267
PDF
The products, kinetics, and mechanisms of metal ion-promoted hydrolyses of thioimidate esters and the effects of hydrogen ions on thioimidate ester hydrolyses
Alan J. Hall and Derek P. N. Satchell
pg 1274; DOI:
10.1039/P29760001274
PDF
Hydrolysis of N-cyclohexyl methylthiobenzimidate in the presence of tetrachlorogold(III) ions and the effects of hydrogen, halide, and other ions
Alan J. Hall and Derek P. N. Satchell
pg 1278; DOI:
10.1039/P29760001278
PDF

Issue 12


Front cover

pg X045; DOI:
10.1039/P297600FX045
PDF
Contents pages

pg P045; DOI:
10.1039/P297600FP045
PDF
Back cover

pg X047; DOI:
10.1039/P297600BX047
PDF
Oxidation of cyclic hydrocarbons by cobalt(III) acetate
Leon Verstraelen Maurice Lalmand André J. Hubert and Philippe Teyssié
pg 1285; DOI:
10.1039/P29760001285
PDF
Racemization of sulphoxides with halide ions anchimerically assisted by a carboxy-group. The different behaviour of chloride and bromide ions
Dario Landini Angela Maria Maia and Franco Rolla
pg 1288; DOI:
10.1039/P29760001288
PDF
Reactions of alkyl vinyl ethers catalysed by triethyloxonium hexachloroantimonate and its decomposition products, in particular antimony pentachloride
Daniel D. Eley Derek F. Monk and Colin H. Rochester
pg 1292; DOI:
10.1039/P29760001292
PDF
Crystal structure and absolute configuration of 2,6,6,8-tetramethyltricyclo[6.2.1.0]undecan-7-yl p-bromobenzoate
Emilio L. Ghisalberti Allan H. White and Anthony C. Willis
pg 1300; DOI:
10.1039/P29760001300
PDF
Mechanistic study of syn- and anti-elimination from diastereoisomeric halogenosulphonylethanes
Vito Fiandanese Carmine V. Maffeo Francesco Naso and Ludovico Ronzini
pg 1303; DOI:
10.1039/P29760001303
PDF
Additivity of substituent effects upon proton–fluorine coupling constants in polysubstituted fluorobenzenes
Victor Wray and David N. Lincoln
pg 1307; DOI:
10.1039/P29760001307
PDF
Proton magnetic resonance studies on compounds with bridgehead nitrogen. Part XXXI. Reversible dimerisation of perhydropyrido [1,2-c][1,3]oxazepines; X-ray analysis of a fourteen-membered macrocyclic dimer; conformational analysis of perhydropyrido [1,2-c][1,3]oxazepines
Rosalind Cahill Trevor A. Crabb and Donald A. Whiting
pg 1312; DOI:
10.1039/P29760001312
PDF
The SN mechanism in aromatic compounds. Part XL. Activating effects of groups attached to the ring by a sulphur atom
Joseph Miller and Kai-Yan Wan
pg 1320; DOI:
10.1039/P29760001320
PDF
Mechanism of the electrophilic iodination of 1,3-diarylallenes
Anton J. G. van Rossum and Rutger J. F. Nivard
pg 1322; DOI:
10.1039/P29760001322
PDF
Conformations of peptides in solution by nuclear magnetic resonance spectroscopy. Part IV. Conformations of valinomycin determined from homoallylic proton coupling across peptide bonds
David B. Davies and Md. Abu Khaled
pg 1327; DOI:
10.1039/P29760001327
PDF
Phenanthronorbornyl cation: a conformation-locked 1,2-diarylnorbornyl cation. Part II. 13C Nuclear magnetic resonance spectroscopy
Martin C. Grossel and M. John Perkins
pg 1334; DOI:
10.1039/P29760001334
PDF
Mechanism of the oxidation of glyoxylic and pyruvic acids by periodate
László Maros Ibolya Molnár-Perl and László Kövér
pg 1337; DOI:
10.1039/P29760001337
PDF
Stereochemistry of reduction of umbellulone (thuj-3-en-2-one) and isodihydroumbellulone (4H-thujan-2-one)
Collette M. Holden John C. Rees Stephen P. Scott and David Whittaker
pg 1342; DOI:
10.1039/P29760001342
PDF
Rearrangements of the thujan-3-yl cation
Collette M. Holden and David Whittaker
pg 1345; DOI:
10.1039/P29760001345
PDF
Cyclohexadienones. Use of the dienone–phenol rearrangement in measuring migratory aptitudes of alkyl groups
James W. Pilkington and Anthony J. Waring
pg 1349; DOI:
10.1039/P29760001349
PDF
Stereochemistry of anticholinergic agents. Part VIII. Crystal and molecular structure of O-benzoyltropine hydrochloride
Thomas A. Hamor
pg 1359; DOI:
10.1039/P29760001359
PDF
Positive and negative ion mass spectra of nitro- and polynitro-1,5- and -2,3-dimethylnaphthalenes
Stephen R. Robinson Clifford H. J. Wells Robert B. Turner and John F. J. Todd
pg 1363; DOI:
10.1039/P29760001363
PDF
Brnsted exponents in the proton abstraction from derivatives of ethyl -benzylacetoacetate, 3-benzylpentane-2,4-dione, and benzylmalononitrile
Ronald P. Bell and Stephen Grainger
pg 1367; DOI:
10.1039/P29760001367
PDF
Reductive dehalogenation of 2-iodobenzothiazole with alkanethiols
Giuseppe Bartoli Leonardo Di Nunno Saverio Florio Michele Fiorentino and Paolo E. Todesco
pg 1371; DOI:
10.1039/P29760001371
PDF
Kinetics and mechanism of addition of acids to olefins. Part 2. Addition of trifluoroacetic acid to (+)-(R)-limonene in weakly polar media
R. M. G. Roberts
pg 1374; DOI:
10.1039/P29760001374
PDF
Crystal and molecular structures of silver N1-(3-pyridyl)sulphanilamide
David S. Cook and Michael F. Turner
pg 1379; DOI:
10.1039/P29760001379
PDF
Crystal structure of 10-phenylphenoxaphosphine
Frederick G. Mann Ian T. Millar H. Marcus Powell and David J. Watkin
pg 1383; DOI:
10.1039/P29760001383
PDF
Crystal structure of the growth inhibitor, maleic hydrazide(1,2-dihydropyridazine-3,6-dione)
Peter D. Cradwick
pg 1386; DOI:
10.1039/P29760001386
PDF
The kinetics and mechanisms of aromatic halogen substitution. Part XXXIII. Kinetics and products of chlorination of some aryl acetates
Peter B. D. de la Mare Brian N. B. Hannan and Neil S. Isaacs
pg 1389; DOI:
10.1039/P29760001389
PDF
The kinetics of the reactions of piperidine, n-butylamine, morpholine, and benzylamine with 1-fluoro- and 1-chloro-2,4-dinitrobenzenes in acetonitrile
Dapo Ayediran Titus O. Bamkole and Jack Hirst
pg 1396; DOI:
10.1039/P29760001396
PDF
X-Ray structures of hymenoxon and hymenolane : pseudoguaianolides isolated from Hymenoxys odorata DC. (Bitterweed)
Roger C. Pattersen and Hyeong L. Kim
pg 1399; DOI:
10.1039/P29760001399
PDF
Synthesis and crystal and molecular structure of 1-ethylthio-2-(p-nitrophenyl)-2-(triphenylphosphonio)ethenethiolate
Gabriella Bombieri Eleonora Forsellini Ugo Chiacchio Pasqualina Fiandaca Giovanni Purrello Elisabetta Foresti and Rodolfo Graziani
pg 1404; DOI:
10.1039/P29760001404
PDF
Radiation chemistry of acetals. Part 1. Photolysis ( 185 nm) of formaldehyde dimethyl acetal in the liquid phase
Heinz-Peter Schuchmann and Clemens von Sonntag
pg 1408; DOI:
10.1039/P29760001408
PDF
Reactions over metal catalysts. Part II. Hydrogenolysis of 3,3-dimethylnortricyclene and nortricyclene-3-spirocyclopropane
M. Naseem Akhtar John J. Rooney and W. Roy Jackson
pg 1412; DOI:
10.1039/P29760001412
PDF
Conformations of some semi-rigid neuroleptic drugs. Part 1. Crystal structures of loxapine, clozapine, and HUF-2046 monohydrate {2-chloro-11-(4-methylpiperazin-1-yl)dibenzo[b,f][1,4]oxazepine, 8-chloro-11-(4-methylpiperazin-1-yl)dibenzo[b,e][1,4]diazepine, and 2-chloro-11(4-methylpiperazin-1-yl)dibenzo[b,e][1,4]diazepine monohydrate}
Trevor J. Petcher and Hans-Peter Weber
pg 1415; DOI:
10.1039/P29760001415
PDF
Gas-phase thermolysis of sulphur compounds. Part I. Di-t-butyl disulphide
G. Martin and N. Barroeta
pg 1421; DOI:
10.1039/P29760001421
PDF
Kinetics and mechanism of the acid-catalysed hydrolysis of N-methyl-N-phenylsulphamate
William J. Spillane Noel Regan and Francis L. Scott
pg 1424; DOI:
10.1039/P29760001424
PDF
Tautomeric pyridines. Part XV. Pyridone–hydroxypyridine equilibria in solvents of differing polarity
Judit Frank and Alan R. Katritzky
pg 1428; DOI:
10.1039/P29760001428
PDF
Pyrolysis of S-alkyl-S-phenyl-N-p-tolylsulphonylsulphimides with no -hydrogen atoms
Tetsuo Aida Naomichi Furukawa and Shigeru Oae
pg 1432; DOI:
10.1039/P29760001432
PDF
Mechanism of the reaction of N-arylsulphonylsulphimides with trivalent phosphorus compounds
Tetsuo Aida Naomichi Furukawa and Shigeru Oae
pg 1438; DOI:
10.1039/P29760001438
PDF
Direct N-methylation of 2-pyridylphosphonic acids by diazomethane
John S. Loran Richard A. Naylor and Andrew Williams
pg 1444; DOI:
10.1039/P29760001444
PDF
Crystal and molecular structures of (–)-7,7-dibromo-3,3,3,3,5,5hexamethyl-1,1-spirobi-indane-6,6-diol and ()-3,3,3,3,5,5-hexamethyl-1,1-spirobi-indane
Motoo Shiro Sanji Hagishita and Kooru Kuriyama
pg 1447; DOI:
10.1039/P29760001447
PDF
Intramolecular fluorescence quenching of anthracene by heterocyclic ligands
G. Michael Blackburn Geoffrey Lockwood and Vishnu Solan
pg 1452; DOI:
10.1039/P29760001452
PDF

Issue 13


Front cover

pg X049; DOI:
10.1039/P297600FX049
PDF
Contents pages

pg P049; DOI:
10.1039/P297600FP049
PDF
Back cover

pg X051; DOI:
10.1039/P297600BX051
PDF
Crystal and molecular structure of biliverdin dimethyl ester
William S. Sheldrick
pg 1457; DOI:
10.1039/P29760001457
PDF
Classical carbonium ions. Part VIII. Deamination of cis- and trans-4-t-butylcyclohexylamines
Howard Maskill and Mark C. Whiting
pg 1462; DOI:
10.1039/P29760001462
PDF
Reaction of 1,3-dienes with sulphur dioxide. Part 1. Thermal decomposition of 2,5-dihydrothiophen 1,1-dioxides
Neil S. Isaacs and Abdulhameed A. R. Laila
pg 1470; DOI:
10.1039/P29760001470
PDF
Electron transfer in the photochemistry of substituted benzoate and naphthoate esters
John D. Coyle and David H. Kingston
pg 1475; DOI:
10.1039/P29760001475
PDF
The concept of a hierarchy of unimolecular reactions in a homologous series. Prediction of the unimolecular chemistry of some saturated carbenium ions
Richard D. Bowen and Dudley H. Williams
pg 1479; DOI:
10.1039/P29760001479
PDF
The nature of substituent electronic effects; the existence of the -inductive effect
Robert T. C. Brownlee Graeme Butt Mun P. Chan and Ronald D. Topsom
pg 1486; DOI:
10.1039/P29760001486
PDF
X-Ray study of (S,SS/R,SR)-1-(p-bromophenyl)ethyl t-butyl sulphoxide and conformational analysis of diastereoisomeric pairs of 1-phenylethyl t-butyl sulphoxides
Yoshio Kodama Ken Nishihata Motohiro Nishio and Yoichi Litaka
pg 1490; DOI:
10.1039/P29760001490
PDF
Linear free energy ortho-correlations in the thiophen series. Part III. The kinetics of piperidino-substitution of some 3-X-5-nitro-2-thienyl phenyl sulphones in methanol
Domenico Spinelli Giovanni Consiglio and Renato Noto
pg 1495; DOI:
10.1039/P29760001495
PDF
Hydration of acetaldehyde catalysed by micellar triton X-100 in carbon tetrachloride
Omar A. El Seoud
pg 1497; DOI:
10.1039/P29760001497
PDF
Dynamic stereochemistry of imines and derivatives. Part IX. The mechanism of EZ isomerization in N-alkylimines
W. Brian Jennings Salim Al-Showiman Derek R. Boyd and Rose M. Campbell
pg 1501; DOI:
10.1039/P29760001501
PDF
Solvolysis of endo- and exo-bicyclo[3.2.1]octan-3-yl toluene-p-sulphonates. Part 1. Product analysis
Mrs. R. M. Banks and H. Maskill
pg 1506; DOI:
10.1039/P29760001506
PDF
Mass spectra of 1,3-diarylazetidin-3-ols and related compounds
Jim Clark and John Hill
pg 1514; DOI:
10.1039/P29760001514
PDF
Electrophilic additions to acetylenes. Part VI. Addition of t-butyl chloride and benzyl chloride to alkynes
Franco Marcuzzi and Giovanni Melloni
pg 1517; DOI:
10.1039/P29760001517
PDF
Kinetics of reduction of acetophenones by alkali-metal alkoxides, and the mechanism of reduction of ketones by borohydride
Raymond D. Burnett and David N. Kirk
pg 1523; DOI:
10.1039/P29760001523
PDF
Natural abundance nitrogen-15 nuclear magnetic resonance spectroscopy. Medium effects on the nitrogen-15 chemical shifts of small peptides
Daniela Gattegno Geoffrey E. Hawkes and Edward W. Randall
pg 1527; DOI:
10.1039/P29760001527
PDF
Enthalpies of transfer involving ionic transition states : the redundance of extrathermodynamic assumptions
Victor Gold
pg 1531; DOI:
10.1039/P29760001531
PDF
Reactions of Keten. Part VI. Kinetics of gas-phase reactions with halogenated and unsaturated acids, formic acid, and acetic [2H]acid
Peter G. Blake and Mohammad Hassan Baghal Vayjooee
pg 1533; DOI:
10.1039/P29760001533
PDF
Structure of the short wavelength photoisomers of bianthrone analogues
Raphael Korenstein Karol A. Muszkat and Georg Seger
pg 1536; DOI:
10.1039/P29760001536
PDF
Nucleophilic displacement in polyhalogenoaromatic compounds. Part 1. Kinetics of reaction of polychlorofluorobenzene derivatives
Roger Bolton and John P. B. Sandall
pg 1541; DOI:
10.1039/P29760001541
PDF
Nucleophilic displacement in polyhalogenoaromatic compounds. Part 2. Kinetics of halogen displacement from bromopolyfluoroaromatic compounds
Roger Bolton and John P. B. Sandall
pg 1545; DOI:
10.1039/P29760001545
PDF
The energetics of a readily occurring intramolecular hydride shift
Rodney S. Henry Frank G. Riddell William Parker and C. Ian F. Watt
pg 1549; DOI:
10.1039/P29760001549
PDF
Studies on the sulphonation of anthracene. Part 1. Sulphonation in neutral or basic solvents
John O. Morley
pg 1554; DOI:
10.1039/P29760001554
PDF
Studies on the sulphonation of anthracene. Part 2. Sulphonation in acetic acid and related solvents
John O. Morley
pg 1560; DOI:
10.1039/P29760001560
PDF
The conformational analysis of saturated heterocycles. Part 76. Ring and nitrogen inversion in cis- and trans-1, 4, 5, 8-tetramethyldecahydropyrazino[2,3-b]pyrazine
Ian J. Ferguson Alan R. Katritzky and (Miss) Ranjan Patel
pg 1564; DOI:
10.1039/P29760001564
PDF
Kinetics and mechanisms of the reactions of organic cation radicals and dications. Part V. Kinetics of thermodynamically unfavourable electron transfer reactions between cation radicals and aromatic compounds
Ulla Svanholm and Vernon D. Parker
pg 1567; DOI:
10.1039/P29760001567
PDF
Linear free energy relationships. Part VII. Synthesis and properties of a novel double-barrelled solvatochromic compound
Harry W. Gibson and Fowtrey C. Bailey
pg 1575; DOI:
10.1039/P29760001575
PDF
Carbon-13 chemical shifts and substituent effects in 4-substituted camphors, N-nitrocamphorimines, and diazocamphors
David G. Morris and A. Malcolm Murray
pg 1579; DOI:
10.1039/P29760001579
PDF
Conformational analysis of cyclic amines using carbon-13 chemical shift measurements: dependence of conformation upon ionisation state and solvent
John G. Batchelor
pg 1585; DOI:
10.1039/P29760001585
PDF
Bi- and ter-molecular electron donor–acceptor complex formation between hexamethylbenzene and 1,3,5-trinitrobenzene, and also between NNNN-tetramethyl-p-phenylenediamine and 1,3,5-trinitrobenzene in solution
Ray J. Bailey John A. Chudek and Roy Foster
pg 1590; DOI:
10.1039/P29760001590
PDF
Kinetics of the addition of hydroxide ions to substituted benzaldehydes
Ronald P. Bell and Poul E. Sørensen
pg 1594; DOI:
10.1039/P29760001594
PDF
The carbon-13 nuclear magnetic resonance spectra of the deoxyfluoro-D-glucoses, 2-deoxy-2-fluoro-D-mannose, and 4-deoxy-4-fluoro-D-galactose. Orientational and substituent effects upon nJFC
Victor Wray
pg 1598; DOI:
10.1039/P29760001598
PDF
Kinetics and isotope effects in proton transfers from 3-bromo- and 3-nitro-(+)-camphor
Ronald P. Bell and Stephen Grainger
pg 1606; DOI:
10.1039/P29760001606
PDF
Tautomerism of diazidopyrimidines. Molecular structure of 2,4-diazido-5-iodopyrimidine
David W. Allen David J. Buckland and Ian W. Nowell
pg 1610; DOI:
10.1039/P29760001610
PDF

Issue 14


Front cover

pg X053; DOI:
10.1039/P297600FX053
PDF
Contents pages

pg P053; DOI:
10.1039/P297600FP053
PDF
Back cover

pg X055; DOI:
10.1039/P297600BX055
PDF
Nucleophilic reactivity of organophosphorus compounds. Part 3. Kinetics and mechanism of the reaction of phosphorus acids with keten OO-acetals in aprotic medium
Robert L. Dyer Paul G. Le Grâs and C. Dennis Hall
pg 1613; DOI:
10.1039/P29760001613
PDF
Retentive solvolysis. Part XI. Retentive phenolyses of optically active secondary and tertiary systems without a group imposing configurational restriction
Kunio Okamoto Tomomi Kinoshita Takahiro Oshida Takashi Yamamoto Yuji Ito and Masahiro Dohi
pg 1617; DOI:
10.1039/P29760001617
PDF
Influence of aprotic solvents on the O–D stretching band of methan[2H]ol
Alan G. Burden Geoffrey Collier and John Shorter
pg 1627; DOI:
10.1039/P29760001627
PDF
Koenigs–Knorr reactions. Part II. A mechanistic study of mercury(II) cyanide-promoted reactions of 2,3,4,6-tetra-O-methyl--D-glucopyranosyl bromide with cyclohexanol in benzene–nitromethane
Jerry E. Wallace and Leland R. Schroeder
pg 1632; DOI:
10.1039/P29760001632
PDF
Relative reactivities of ion-pairs of the 1,3-diphenylallyl carbanion towards fluorene
Geoffrey C. Greenacre and Ronald N. Young
pg 1636; DOI:
10.1039/P29760001636
PDF
Detritiation kinetics of acetophenones in highly acidic media
Derek W. Earls
pg 1641; DOI:
10.1039/P29760001641
PDF
Polarisation and polarisability study of some chlorinated cyclodiene insecticides
Kingsley E. Calderbank and Raymond K. Pierens
pg 1645; DOI:
10.1039/P29760001645
PDF
Comparison of methanolysis of a series of p-benzyloxybenzoyl chlorides with that of benzoyl, p-phenoxybenzoyl, and p-methoxybenzoyl chlorides
(the late) Paulo Carvalho Ferreira Nilo Zengo Kiyan Yukino Miyata and Joseph Miller
pg 1648; DOI:
10.1039/P29760001648
PDF
Kinetics and mechanism of oxidation pathways of some catecholamines with periodic acid
Ezio Pelizzetti Edoardo Mentasti and Edmondo Pramauro
pg 1651; DOI:
10.1039/P29760001651
PDF
Electron impact studies. Part CIV. Cyclisation reactions of negative ions. The o-O2NC6H4(CHCH)nCOR system
John H. Bowie and Sompong Janposri
pg 1656; DOI:
10.1039/P29760001656
PDF
Revised assignment of the electron spin resonance spectrum obtained during photolysis of N-(diphenylmethylene)methylthiomethylamine N-oxide. The bis(methylthiomethyl) nitroxide radical
George Brunton and Keith U. Ingold
pg 1659; DOI:
10.1039/P29760001659
PDF
Equilibrium study of biphenyl-2-ol by infrared spectroscopy
Toshio Kinugasa Michiko Nakamura and Shinichi Ueji
pg 1663; DOI:
10.1039/P29760001663
PDF
Conformations of conjugated hydrocarbons. Part 1. A spectroscopic and thermodynamic study of buta-1,3-diene and 2-methylbuta-1,3-diene (isoprene)
David A. C. Compton William O. George and William F. Maddams
pg 1666; DOI:
10.1039/P29760001666
PDF
The interpretation of carbon nuclear magnetic resonance shifts. Part 2. The alkane (empirical) shielding parameters, and an absolute scale for carbon shielding
Joan Mason
pg 1671; DOI:
10.1039/P29760001671
PDF
Chiroptical properties of lactones. Part III. Electronic rotatory strengths of the n* transition in -unsaturated -lactone systems
Harry Kreigh and Frederick S. Richardson
pg 1674; DOI:
10.1039/P29760001674
PDF
Crystal and molecular structure of a carbohydrate-derived oxetan-3-one. Definitive evidence for a novel participation of a pyranose ring oxygen atom
Arnaud Ducruix Claudine Pascard Serge David and Jean-Claude Fischer
pg 1678; DOI:
10.1039/P29760001678
PDF
Organic anions. Part 1. Equilibration of 1,3-diarylpropenes
Richard J. Bushby and Gerald J. Ferber
pg 1683; DOI:
10.1039/P29760001683
PDF
Organic anions. Part 2. Spectroscopic studies of 1,3-diarylpropenide ions
Richard J. Bushby and Gerald J. Ferber
pg 1688; DOI:
10.1039/P29760001688
PDF
Organic anions. Part 3. Charge control versus product stability control in the protonation of 1,3-diarylpropenide ions
Richard J. Bushby and Gerald J. Ferber
pg 1695; DOI:
10.1039/P29760001695
PDF
Nucleophilic addition to linear nitrilium ions (–CN–) leading to single isomers. Isolation of relatively stable isoimides and their rearrangement to imides limited by substrate ZE isomerisation
Margaret T. McCormack and Anthony F. Hegarty
pg 1701; DOI:
10.1039/P29760001701
PDF
Electro-organic reactions. Part IX. Mechanism of the Kolbe reaction; stereochemistry of reaction of anodically generated cyclohexyl radicals and cations
Geoffrey E. Hawkes James H. P. Utley and George B. Yates
pg 1709; DOI:
10.1039/P29760001709
PDF
Crystal and molecular structure of 15-bromolongibornane-8,9-dione
Tayur N. Guru Row and Kailasam Venkatesan
pg 1716; DOI:
10.1039/P29760001716
PDF
Direction of ring-opening of ring-substituted cyclopropyl(stannyloxy)methyl and cyclopropyl(hydroxy)methyl radicals: preferential formation of primary alkyl radicals
Alwyn G. Davies Brenda Muggleton Jean-Yves Godet Michel Pereyre and Jean-Claude Pommier
pg 1719; DOI:
10.1039/P29760001719
PDF
Polar substituents and the luminescence of organic compounds
Leslie A. King
pg 1725; DOI:
10.1039/P29760001725
PDF
Structure of icetexone, a diterpene quinone from Salvia ballotaeflorae
Zenei Taira William H. Watson and Xorge A. Dominguez
pg 1728; DOI:
10.1039/P29760001728
PDF
Topochemistry. Part 38. Photodimerisation in mixed crystals of trans-cinnamamides and of trans-stilbenes
Mendel D. Cohen and Roselyne Cohen
pg 1731; DOI:
10.1039/P29760001731
PDF
Substitution at saturated carbon. Part XX. The effect of 39 solvents on the free energy of Et3N, EtI, and the Et3N–EtI transition state. Comparison with solvent effects on the equilibria Et3N + EtI Et4N+I and Et3N + EtI Et4N++ I
Michael H. Abraham and Priscilla L. Grellier
pg 1735; DOI:
10.1039/P29760001735
PDF
Kinetics of desulphonative double Smiles' rearrangement of N-(2-hydroxyalkyl)-p-nitrobenzenesulphonamides
Anthony C. Knipe and Joseph Lound-Keast
pg 1741; DOI:
10.1039/P29760001741
PDF
Intramolecular general base catalysis in the hydrolysis of 3-dimethylaminopropionates
Anthony J. Kirby and Gordon J. Lloyd
pg 1748; DOI:
10.1039/P29760001748
PDF
Structure and efficiency in intramolecular and enzymic catalysis: intramolecular general base catalysis. Hydrolysis of monoaryl malonates
Anthony J. Kirby and Gordon J. Lloyd
pg 1753; DOI:
10.1039/P29760001753
PDF
The E1cb mechanism for ester hydrolysis. Evidence for a dianion intermediate in the hydrolysis of aryl malonate anions
Anthony J. Kirby and Gordon J. Lloyd
pg 1762; DOI:
10.1039/P29760001762
PDF

Issue 15


Front cover

pg X057; DOI:
10.1039/P297600FX057
PDF
Contents pages

pg P057; DOI:
10.1039/P297600FP057
PDF
Back cover

pg X059; DOI:
10.1039/P297600BX059
PDF
The photo-oxidation of aliphatic alcohols as monolayers on aqueous solutions of 1,1-dimethyl-4,4-bipyridylium (paraquat) dichloride
Norman M. D. Brown David J. Cowley and William J. Murphy
pg 1769; DOI:
10.1039/P29760001769
PDF
Kinetics of base-catalysed condensation of 5-methylfuran-2(3H)-one with 2-hydroxybenzaldehyde
Ignazio R. Bellobono Alma Dal Pozzo and Mario T. Cataldi
pg 1773; DOI:
10.1039/P29760001773
PDF
Aromatic sulphonation. Part 52. Ionization, sulphation, sulphonation, and alkylation of -phenylalkan-1-ols in sulphuric acid
Ankie Koeberg-Telder and Hans Cerfontain
pg 1776; DOI:
10.1039/P29760001776
PDF
Aromatic sulphonation. Part 53. Kinetics and mechanism of sulphonation of -phenylalkane-1-sulphonic acids in sulphuric acid. Comparison of the side-chain SO3H and OSO3H substituent effects
Hans Cerfontain and (Mrs.) Zwaantje R. H. Schaasberg-Nienhuis
pg 1780; DOI:
10.1039/P29760001780
PDF
Equilibria and reactions of acetylsulphuric acid in liquid sulphur dioxide
Enzo Montoneri Mirco Fornaroli Luigi Giuffré Ezio Tempesti and Giancarlo Sioli
pg 1784; DOI:
10.1039/P29760001784
PDF
The role of intermediate complexes in benzofuran protonations
Estanislao Silla Juan Bertrán Enric Canadell and J. I. Fernández-Alonso
pg 1789; DOI:
10.1039/P29760001789
PDF
Conformational studies by dynamic nuclear magnetic resonance. Part 4. Rotational isomers and torsional barriers of pyridinecarbaldehydes
Lodovico Lunazzi Dante Macciantelli and Giovanni Cerioni
pg 1791; DOI:
10.1039/P29760001791
PDF
Nematic phase nuclear magnetic resonance investigations of rotational isomerism. Part IV. Conformational study on the rotamers of 3,3-bithienyl
Lodovico Lunazzi Franco Salvetti and C. Alberto Veracini
pg 1796; DOI:
10.1039/P29760001796
PDF
The carbonyl group frequency. Part VI. Alkyl carbonates
J. Sydney Byrne Paul F. Jackson and Keith J. Morgan
pg 1800; DOI:
10.1039/P29760001800
PDF
Kinetics of the oxidation of some meta- and para-substituted dimethylanilines with lead tetra-acetate
Guido Galliani Bruno Rindone and Pier Luigi Beltrame
pg 1803; DOI:
10.1039/P29760001803
PDF
Linear free energy ortho-correlations in the thiophen series. Part IV. Kinetics of alkaline hydrolysis of some methyl 3-substituted thiophen-2-carboxylates in aqueous methanol
Domenico Spinelli Renato Noto Giovanni Consiglio and Alba Storace
pg 1805; DOI:
10.1039/P29760001805
PDF
Crystal and molecular structure of thiosemicarbazide hydrochloride
Leandro Coghi Anna Maria Manotti Lanfredi and Antonio Tiripicchio
pg 1808; DOI:
10.1039/P29760001808
PDF
Reduction of some ketones using sulphurated sodium borohydride (NaBH2S3) : kinetics and mechanism
V. M. Sadagopa Ramanujam and Norman M. Trieff
pg 1811; DOI:
10.1039/P29760001811
PDF
Vapour-phase chemistry of arenes. Part 3. Vapour-phase chlorination of benzene derivatives catalysed by ultraviolet light
Wim Dorrepaal and Robert Louw
pg 1815; DOI:
10.1039/P29760001815
PDF
Chiroptical properties of cyclo-L-cystine
Robin W. Strickland and Frederick S. Richardson
pg 1818; DOI:
10.1039/P29760001818
PDF
Chlorinated pyridine compounds: quantum chemical calculations and chlorine-35 nuclear quadrupole resonance frequencies
Mavis Redshaw
pg 1821; DOI:
10.1039/P29760001821
PDF
The electron spin resonance spectra of alkyl aryl ether radical cations
Willliam T. Dixon and David Murphy
pg 1823; DOI:
10.1039/P29760001823
PDF
1,3-Dipolar character of six-membered aromatic rings. Part XXIX. Kinetic rates and equilibria for the addition of 2-electron addends to 3-oxidopyridinium betaines
Georges Guiheneuf Christian Laurence and Alan R. Katritzky
pg 1829; DOI:
10.1039/P29760001829
PDF
Crystal structure of a very hindered olefin: 1,1-diphenyl-2,2-di-t-butylethylene at –155 C
Angelo Mugnoli and Massimo Simonetta
pg 1831; DOI:
10.1039/P29760001831
PDF
Nucleophilic character of acyl radicals. Absolute rate constant for the acylation of protonated benzothiazole by pivaloyl radical
Marta Bellatti Tullio Caronna Attilio Citterio and Francesco Minisci
pg 1835; DOI:
10.1039/P29760001835
PDF
Denitrosation of N-methyl-N-nitrosotoluene-p-sulphonamide in acid solution
D. Lyn H. Williams
pg 1838; DOI:
10.1039/P29760001838
PDF
Kinetics of oxidation of organic compounds by silver(II) in aqueous perchloric acid solution. Part 2. Aliphatic carboxylic acids
Edoardo Mentasti Ezio Pelizzetti and Claudio Baiocchi
pg 1841; DOI:
10.1039/P29760001841
PDF
Dipole moment, spectroscopic, and theoretical study of di-2-pyridyl sulphones
Adriano Bigotto Vinicio Galasso Giuseppe C. Pappalardo and Giuseppe Scarlata
pg 1845; DOI:
10.1039/P29760001845
PDF
The photochemistry of benz[de]anthracen-7-ones. Part III. Fluorescence quantum yield and continuous photolysis studies
Peter Bentley and John F. McKellar
pg 1850; DOI:
10.1039/P29760001850
PDF
Molecular polarisability. The conformations of some substituted pentafluorobenzenes
Manuel J. Aroney Mrs. Georgina Cleaver Raymond K. Pierens and Raymond J. W. Le Fèvre
pg 1854; DOI:
10.1039/P29760001854
PDF
Evidence for formation of carbanions in cleavage of carbon–silicon bonds by methanolic sodium methoxide. Some large kinetic isotope effects for reactions of carbanions with methanol
Colin Eaborn David R. M. Walton and Giancarlo Seconi
pg 1857; DOI:
10.1039/P29760001857
PDF
The conformational analysis of saturated heterocycles. Part 72. Tetrahydro-1,3,4-oxadiazines
Ian J. Ferguson Alan R. Katritzky and David M. Read
pg 1861; DOI:
10.1039/P29760001861
PDF
Thermal isomerization of 3,6-dimethyltricyclo[3.1.0.0]hexane
Henry M. Frey Henning Hopf and Robert A. Smith
pg 1865; DOI:
10.1039/P29760001865
PDF
Nuclear quadrupole resonance and stereochemistry. Part 6. Transmission of substituent effects through a double bond
Z. Ardalan de Weck F. Delay M. Geoffroy E. A. C. Lucken and S. Masson
pg 1867; DOI:
10.1039/P29760001867
PDF
Basicity and nucleophilic reactivity of carbonyl-stabilized sulphimides
Hideo Kise Yukio Sugiyama and Manabu Sen
pg 1869; DOI:
10.1039/P29760001869
PDF
Correlation of the loss of solvent with the crystal structure of a 1 : 1 solvate. Indanetrione 2-(N-p-t-butylbenzoyl-N-phenylhydrazone) acetone solvate
Sherrill A. Puckett Iain C. Paul and David Y. Curtin
pg 1873; DOI:
10.1039/P29760001873
PDF
Structures and conformations of the fourteen-membered ring diterpene ovatodiolide and its acid cyclization product: nuclear Overhauser effect studies in solution and X-ray crystal structure analyses of ovatodiolide and ovatodiolic acid
Raoul Toubiana Marie-Josèphe Toubiana Andrew T. McPhail Richard W. Miller and Kazuo Tori
pg 1881; DOI:
10.1039/P29760001881
PDF
Bridgehead -deuterium secondary kinetic isotope effect in the solvolysis of endo-norbornan-2-yl p-bromobenzenesuiphonate
H. Maskill
pg 1889; DOI:
10.1039/P29760001889
PDF
Kinetics of solvolysis of substituted -bromo-2-acetonaphthones in aqueous ethanol
P. Ananthakrishna Nadar and C. Gnanasekaran
pg 1893; DOI:
10.1039/P29760001893
PDF
Carbonylation of organomagnesium compounds: catalysis by hexamethylphosphoric triamide
Wilhelmus J. J. M. Sprangers and Robert Louw
pg 1895; DOI:
10.1039/P29760001895
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Photochemical oxetan formation: the Paterno–Bchi reaction of aliphatic aldehydes and ketones with alkenes and dienes
Carel W. Funke and Hans Cerfontain
pg 1902; DOI:
10.1039/P29760001902
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Electrophilic participation in phosphonodiester hydrolysis
Richard A. Naylor and Andrew Williams
pg 1908; DOI:
10.1039/P29760001908
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Role of hydrogen bonding in the mechanism of hydrogen atom abstraction from alkyl-substituted phenols by polyvinyl acetate radicals
Miklós Simonyi Julianna Kardos Ilona Fitos Ilone Kovács and Jan Pospiil
pg 1913; DOI:
10.1039/P29760001913
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Molecular mechanics calculations on lactones; an interpretation of the preferential C(8) relactonization of germacranolides containing C(6) and C(8) lactonizable -oxygen functions
Michael H. P. Guy George A. Sim and David N. J. White
pg 1917; DOI:
10.1039/P29760001917
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Additivity of substituent effects in the alkaline hydrolysis of alkyl benzoates
Jameel Farooqi Peter H. Gore and Abdur Rahim
pg 1921; DOI:
10.1039/P29760001921
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